23258
氯甲酸-2,2,2-三氯乙酯
purum, ≥98.0% (NT)
别名:
三氯乙氧基甲酰氯
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关于此项目
线性分子式:
ClCOOCH2CCl3
化学文摘社编号:
分子量:
211.86
Beilstein:
970619
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
蒸汽压
0.06 psi ( 20 °C)
质量水平
等级
purum
方案
≥98.0% (NT)
折射率
n20/D 1.471 (lit.)
n20/D 1.471
沸点
171-172 °C (lit.)
密度
1.539 g/mL at 25 °C (lit.)
官能团
chloro
储存温度
2-8°C
SMILES字符串
ClC(=O)OCC(Cl)(Cl)Cl
InChI
1S/C3H2Cl4O2/c4-2(8)9-1-3(5,6)7/h1H2
InChI key
LJCZNYWLQZZIOS-UHFFFAOYSA-N
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应用
胺和醇的基团保护剂；用于叔胺的脱甲基化
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Inhalation - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
M. Imoto et al.
Bulletin of the Chemical Society of Japan, 60, 2205-2205 (1987)
F. Farina et al.
Tetrahedron Letters, 32, 1109-1109 (1991)
X.S. He et al.
Synthetic Communications, 20, 2177-2177 (1990)
J O Kuye et al.
Journal of chromatography, 272(2), 307-313 (1983-02-11)
A specific method for the gas chromatographic determination of chloroquine (CQ) after derivatization with chloroformates, using 9-bromophenanthrene as the internal standard and a column filled with 3% OV-17 on 80-100 mesh Supelcoport is described. Derivatization with chloroformates produced a pyrrolidine
Giampietro Frison et al.
Rapid communications in mass spectrometry : RCM, 19(7), 919-927 (2005-03-05)
A new analytical approach, based on derivatization with 2,2,2-trichloroethyl chloroformate and gas chromatography/mass spectrometry (GC/MS), was investigated for qualitative and quantitative analyses of a large range of amphetamine-related drugs and ephedrines in plasma, urine and hair samples. Sample preparation involved
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