240486
2-甲基-2-丁醇
≥99%, liquid, suitable for synthesis, ReagentPlus®
别名:
tert-Amyl alcohol, 叔戊醇
产品名称
2-甲基-2-丁醇, ReagentPlus®, ≥99%
蒸汽密度
3 (vs air)
质量水平
蒸汽压
12 mmHg ( 20 °C)
产品线
ReagentPlus®
方案
≥99%
表单
liquid
自燃温度
819 °F
expl. lim.
9 %
dilution
(for general lab use)
折射率
n20/D 1.405 (lit.)
沸点
102 °C (lit.)
mp
−12 °C (lit.)
密度
0.805 g/mL at 25 °C (lit.)
官能团
hydroxyl
SMILES字符串
CCC(C)(C)O
InChI
1S/C5H12O/c1-4-5(2,3)6/h6H,4H2,1-3H3
InChI key
MSXVEPNJUHWQHW-UHFFFAOYSA-N
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一般描述
2-甲基-2-丁醇是一种空间位阻醇。
应用
2-甲基-2-丁醇可用作以下工艺中的溶剂：
也可用于与浓盐酸反应制备 2-氯-2-甲基丁烷。
- 钯 (II) 催化 邻 -C–H 苯乙酸的烯化反应。
- 铑催化的 N -新戊酰吲哚的 C7 位直接 C-H 官能化。
也可用于与浓盐酸反应制备 2-氯-2-甲基丁烷。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
68.9 °F - closed cup
闪点(°C)
20.5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Rhodium?Catalyzed Regioselective C7?Functionalization of N?Pivaloylindoles.
Xu L, et al.
Angewandte Chemie (International Edition in English), 55(1), 321-325 (2016)
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General kinetic modeling of the selective hydrogenation of 2-methyl-3-butyn-2-ol over a commercial palladium-based catalyst.
Vernuccio S, et al.
Industrial & Engineering Chemistry Research, 54(46), 11543-11551 (2015)
Ternary and Binary LLE Measurements for Solvent (4-Methyl-2-pentanone and 2-Methyl-2-butanol)+ Furfural+ Water between 298 and 401K.
Ma?nnisto? M, et al.
Journal of Chemical and Engineering Data, 61(2), 903-911 (2016)
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