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240486

2-甲基-2-丁醇

≥99%, liquid, suitable for synthesis, ReagentPlus®

别名:

tert-Amyl alcohol, 叔戊醇

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关于此项目

线性分子式:
CH3CH2C(CH3)2OH
化学文摘社编号:
75-85-4
分子量:
88.15
NACRES:
NA.21
PubChem Substance ID:
24854418
UNSPSC Code:
12352100
EC Number:
200-908-9
MDL number:
MFCD00004478
Beilstein/REAXYS Number:
1361351
Assay:
≥99%
Bp:
102 °C (lit.)
Vapor pressure:
12 mmHg ( 20 °C)
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产品名称

2-甲基-2-丁醇, ReagentPlus®, ≥99%

vapor density

3 (vs air)

Quality Level

100

vapor pressure

12 mmHg ( 20 °C)

product line

ReagentPlus®

assay

≥99%

form

liquid

autoignition temp.

819 °F

expl. lim.

9 %

dilution

(for general lab use)

refractive index

n20/D 1.405 (lit.)

bp

102 °C (lit.)

mp

−12 °C (lit.)

density

0.805 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

CCC(C)(C)O

InChI

1S/C5H12O/c1-4-5(2,3)6/h6H,4H2,1-3H3

InChI key

MSXVEPNJUHWQHW-UHFFFAOYSA-N

General description

2-甲基-2-丁醇是一种空间位阻醇。

Application

2-甲基-2-丁醇可用作以下工艺中的溶剂：
  • 钯 (II) 催化 邻 -C–H 苯乙酸的烯化反应。
  • 铑催化的 N -新戊酰吲哚的 C7 位直接 C-H 官能化。

也可用于与浓盐酸反应制备 2-氯-2-甲基丁烷。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

68.9 °F - closed cup

flash_point_c

20.5 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBL3963
STBK9055
STBK3485
STBK0530
STBJ9487

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Yoon Ju Cho et al.
Laboratory animal research, 27(3), 197-203 (2011-10-15)
Tribromoethanol (2,2,2-tribromoethanol, TBE) is a popular injectable anesthetic agent used in mice in Korea. Our goal was to assess the risks associated with side effects (lesions) in the abdominal cavity, especially at high doses. To understand the underlying pathophysiological changes
General kinetic modeling of the selective hydrogenation of 2-methyl-3-butyn-2-ol over a commercial palladium-based catalyst.
Vernuccio S, et al.
Industrial & Engineering Chemistry Research, 54(46), 11543-11551 (2015)
?-tert-alkylation of ketones: 2-tert-pentylcyclopentanone
Organic Syntheses, 62, 95-95 (1984)
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全球贸易项目编号

货号GTIN
240486-5ML04061823360982
240486-100ML04061822468856