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Merck
CN

252883

5,10,15,20-四（4-甲氧基苯基）-21H,23H-吗啡

Dye content 95 %

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关于此项目

经验公式（希尔记法）:
C48H38N4O4
化学文摘社编号:
22112-78-3
分子量:
734.84
NACRES:
NA.47
PubChem Substance ID:
24855247
UNSPSC Code:
12171500
MDL number:
MFCD00012072

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产品名称

5,10,15,20-四（4-甲氧基苯基）-21H,23H-吗啡, Dye content 95 %

InChI

1S/C48H38N4O4/c1-53-33-13-5-29(6-14-33)45-37-21-23-39(49-37)46(30-7-15-34(54-2)16-8-30)41-25-27-43(51-41)48(32-11-19-36(56-4)20-12-32)44-28-26-42(52-44)47(40-24-22-38(45)50-40)31-9-17-35(55-3)18-10-31/h5-28,49,52H,1-4H3/b45-37-,45-38-,46-39-,46-41-,47-40-,47-42-,48-43-,48-44-

SMILES string

COc1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(OC)cc4)c5ccc([nH]5)c(-c6ccc(OC)cc6)c7ccc(n7)c(-c8ccc(OC)cc8)c9ccc2[nH]9

InChI key

PJOJZHHAECOAFH-PJEPRTEXSA-N

form

powder or crystals

composition

Dye content, 95%

λmax

424 nm
653 nm (2nd)

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

Quality Level

100

相关类别

General description

5,10,15,20-四(4-甲基苯基)-21H，23H-卟吩是一种非手性卟啉衍生物。它通过在空气或水界面处的自发对称性破缺形成手性超分子组装体。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBC2545
91197LJ
35996CJ
10296MH
00327HH

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M Belén Ballatore et al.
European journal of medicinal chemistry, 83, 685-694 (2014-07-11)
A covalently linked porphyrin-fullerene C60 dyad 5 was synthesized by 1,3-dipolar cycloaddition using 5-(4-formylphenyl)-10,15,20-tris[3-(N-ethylcarbazoyl)]porphyrin, N-methylglycine and fullerene C60. Methylation of 5 was used to obtain a cationic dyad 6. Spectroscopic properties were compared in toluene, N,N-dimethylformamide (DMF) and toluene/sodium bis(2-ethylhexyl)sulfosuccinate
Maximiliano L Agazzi et al.
Organic & biomolecular chemistry, 18(7), 1449-1461 (2020-02-07)
Chromophore-fullerene C60 hybrids possess interesting properties that enable them to act as heavy atom-free photosensitizers and reactive oxygen species (ROS) producers. Here, two new diketopyrrolopyrrole-C60 conjugates were efficiently synthesized and characterized. The conjugates show broadband absorption in the visible spectral
Chirality amplification of porphyrin assemblies exclusively constructed from achiral porphyrin derivatives.
Chen P, et al.
ChemPhysChem, 7(11), 2419-2423 (2006)

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