29240
环己烯
≥99.0%, contains 100 ppm BHT as inhibitor
别名:
四氢化苯
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关于此项目
经验公式（希尔记法）:
C6H10
化学文摘社编号:
分子量:
82.14
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-807-8
MDL number:
Beilstein/REAXYS Number:
906737
Assay:
≥99.0%
Bp:
83 °C (lit.)
Vapor pressure:
160 mmHg ( 20 °C)
产品名称
环己烯, contains 100 ppm BHT as inhibitor, ≥99.0%
InChI key
HGCIXCUEYOPUTN-UHFFFAOYSA-N
InChI
1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2
SMILES string
C1CCC=CC1
vapor density
2.8 (vs air)
vapor pressure
160 mmHg ( 20 °C)
assay
≥99.0%
autoignition temp.
590 °F
contains
100 ppm BHT as inhibitor
expl. lim.
5 %
evapn. residue
≤0.01%
Quality Level
bp
83 °C (lit.)
mp
−104 °C (lit.)
density
0.811 g/mL at 25 °C (lit.)
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Application
在甘油基溶剂中，以双 [3,5-双（三氟甲基）二苯基] 二硒醚为催化剂，通过过氧化氢环氧化反应合成环己烯氧化物。在过氧钨-草酸络合物催化剂存在下也可发生过氧化氢氧化反应生成己二酸。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F
flash_point_c
-17 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Epoxidation of cyclooctene and cyclohexene with hydrogen peroxide catalyzed by bis [3, 5-bis (trifluoromethyl)-diphenyl] diselenide: Recyclable catalyst-containing phases through the use of glycerol-derived solvents
Garcia-Marin H, et al.
J. Mol. Catal. A: Chem., 334(1), 83-88 (2011)
Catalytic hydrogenation of cyclohexene: 3. Gas-phase and liquid-phase reaction on supported palladium.
Gonzo EE and Boudart M.
J. Catal., 52(3), 462-471 (1978)
Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols.
Yusuke Izawa et al.
Angewandte Chemie (International ed. in English), 52(13), 3672-3675 (2013-02-21)
Hikaru Yanai et al.
Chemical communications (Cambridge, England), 47(25), 7245-7247 (2011-05-25)
In the absence of any additional catalysts, the reactions of (CF(3)SO)(2)CH(2), aldehydes, and 1,3-dienes gave gem-bis(triflyl)cyclohexenes in excellent yields with high regioselectivity. gem-Bis(triflyl)cyclohexene products can be easily converted to the corresponding aryl trifluoromethyl sulfones.
Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) complex: evidence for an iron(IV)-oxo-hydroxo oxidant from O2.
Sayantan Paria et al.
Angewandte Chemie (International ed. in English), 50(47), 11129-11132 (2011-10-01)
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