296295
苯甲醚
anhydrous, 99.7%
别名:
甲基苯基醚, 甲氧基苯
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关于此项目
线性分子式:
CH3OC6H5
化学文摘社编号:
分子量:
108.14
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39023603
UNSPSC Code:
12352112
EC Number:
202-876-1
MDL number:
Beilstein/REAXYS Number:
506892
Grade:
anhydrous
Assay:
99.7%
Bp:
154 °C (lit.)
Vapor pressure:
10 mmHg ( 42.2 °C)
产品名称
苯甲醚, anhydrous, 99.7%
InChI key
RDOXTESZEPMUJZ-UHFFFAOYSA-N
InChI
1S/C7H8O/c1-8-7-5-3-2-4-6-7/h2-6H,1H3
SMILES string
COc1ccccc1
grade
anhydrous
vapor density
3.7 (vs air)
vapor pressure
10 mmHg ( 42.2 °C)
assay
99.7%
form
liquid
autoignition temp.
887 °F
expl. lim.
8 %
impurities
<0.002% water
<0.005% water (100 mL pkg)
evapn. residue
<0.0003%
refractive index
n20/D 1.516 (lit.)
bp
154 °C (lit.)
mp
−37 °C (lit.)
density
0.995 g/mL at 25 °C (lit.)
Quality Level
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Application
苯甲醚可能会通过：
它也可以用作热解实验中木质素初级焦油的替代物。
- 与乙酸中的乙酸酐进行沸石催化的Friedel-Crafts酰化，从而高选择性的形成4-甲氧基苯乙酮。
- 在无溶剂微波辐射下，与苯酸酐进行三氟甲磺酸铋催化的Friedel-Crafts苯甲酰化，以形成4-甲氧基二苯甲酮。
它也可以用作热解实验中木质素初级焦油的替代物。
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
125.1 °F - closed cup
flash_point_c
51.7 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Greener Friedel?Crafts Acylation Using Microwave?Enhanced Reactivity of Bismuth Triflate in the Friedel?Crafts Benzoylation of Aromatic Compounds with Benzoic Anhydride
Tran PH, et al
ChemistrySelect, 2(1), 571-575 (2017)
Detailed kinetic study of anisole pyrolysis and oxidation to understand tar formation during biomass combustion and gasification
Nowakowska M, et al.
Combustion and Flame, 161(6), 1474-1488 (2014)
Selective vapor-phase hydrodeoxygenation of anisole to benzene on molybdenum carbide catalysts.
Lee WS, et al.
J. Catal., 319, 44-53 (2014)
A Novel Friedel-Crafts Acylation Reaction of Anisole for Production of 4-Methoxyacetophenone with High Selectivity and Sufficient Reusability of Mordenite Zeolite Catalyst
Makihara M & Komura K
Green and Sustainable Chemistry, 7(03), 185-185 (2017)
Vibrational spectra and torsional barriers of anisole and some monohalogen derivatives.
Owen NL and Hester RE.
Spectrochimica Acta Part A: Molecular Spectroscopy, 25(2), 343-354 (1969)
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