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Merck
CN

296996

乙酸甲酯

anhydrous, 99.5%

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线性分子式:
CH3COOCH3
化学文摘社编号:
分子量:
74.08
UNSPSC Code:
12352108
NACRES:
NA.21
PubChem Substance ID:
EC Number:
201-185-2
Beilstein/REAXYS Number:
1736662
MDL number:
Grade:
anhydrous
Assay:
99.5%
Bp:
57-58 °C (lit.)
Vapor pressure:
165 mmHg ( 20 °C)
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产品名称

乙酸甲酯, anhydrous, 99.5%

InChI key

KXKVLQRXCPHEJC-UHFFFAOYSA-N

InChI

1S/C3H6O2/c1-3(4)5-2/h1-2H3

SMILES string

COC(C)=O

grade

anhydrous

vapor density

2.55 (vs air)

vapor pressure

165 mmHg ( 20 °C)

assay

99.5%

form

liquid

autoignition temp.

936 °F

expl. lim.

16 %

impurities

<0.003% water
<0.005% water (100 mL pkg)

evapn. residue

<0.0003%

refractive index

n20/D 1.361 (lit.)

bp

57-58 °C (lit.)

mp

−98 °C (lit.)

density

0.934 g/mL at 25 °C

Quality Level

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Application

乙酸甲酯可用于在超临界条件下由菜子油发生非催化酯交换反应制备脂肪酸甲酯和三醋精。

General description

乙酸甲酯(MA)是脂族酯,可通过二甲醚在沸石上发生羰基化来制备。在由乙酸和甲醇制备聚乙烯醇的过程中会生成副产物MA。

Other Notes

货号296996-6X1L的产品即将停产。请订购296996-1L单瓶装,因为其物理参数与上述产品本质相同。

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

8.6 °F - closed cup

flash_point_c

-13 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

法规信息

危险化学品
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分析证书(COA)

Lot/Batch Number

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Reaction kinetics and chemical equilibrium of homogeneously and heterogeneously catalyzed acetic acid esterification with methanol and methyl acetate hydrolysis
Popken T, et al.
Industrial & Engineering Chemistry Research, 39(7), 2601-2611 (2000)
Long Hu et al.
Nature communications, 12(1), 466-466 (2021-01-22)
All-inorganic CsPbI3 perovskite quantum dots have received substantial research interest for photovoltaic applications because of higher efficiency compared to solar cells using other quantum dots materials and the various exciting properties that perovskites have to offer. These quantum dot devices
Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites.
Patricia Cheung et al.
Angewandte Chemie (International ed. in English), 45(10), 1617-1620 (2006-01-31)
A new process for catalyst-free production of biodiesel using supercritical methyl acetate.
Saka S and Isayama Y.
Fuel: The Science and Technology of Fuel and Energy, 88(7), 1307-1313 (2009)
Kinetics of transesterification of methyl acetate and n-octanol catalyzed by cation exchange resins.
Liu Y, et al.
Korean Journal of Chemical Engineering, 30(5), 1039-1042 (2013)

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