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Merck
CN

30620-M

氢氧化钠

puriss. p.a., ACS reagent, reag. Ph. Eur., K ≤0.02%, ≥98%, pellets

别名:

‘苛性钠’

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关于此项目

线性分子式:
NaOH
化学文摘社编号:
分子量:
40.00
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
215-185-5
MDL number:
Assay:
≥98%
Form:
pellets
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InChI key

HEMHJVSKTPXQMS-UHFFFAOYSA-M

InChI

1S/Na.H2O/h;1H2/q+1;/p-1

grade

ACS reagent, puriss. p.a.

agency

reag. Ph. Eur.

vapor density

>1 (vs air)

vapor pressure

<18 mmHg ( 20 °C), 3 mmHg ( 37 °C)

assay

≥98%

form

pellets

technique(s)

titration: suitable

impurities

≤0.0003% total nitrogen (N), ≤0.002% heavy metals (as Ag), ≤1.0% Na2CO3, ≤5 ppm heavy metals (as Pb)

mp

318 °C (lit.)

solubility

water: soluble 1260 g/L at 20 °C

density

2.13 g/cm3

anion traces

chloride (Cl-): ≤10 ppm, phosphate (PO43-): ≤0.0005%, silicate (as SiO2): ≤0.001%, sulfate (SO42-): ≤30 ppm

cation traces

Al: ≤0.0005%, As: ≤0.0001%, Ca: ≤0.0005%, Cu: ≤0.0005%, Fe: ≤5 ppm, Hg: ≤0.05 ppm, K: ≤0.02%, Mg: ≤0.0005%, Ni: ≤0.0005%, Pb: ≤0.0002%, Zn: ≤0.0005%

Quality Level

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General description

Sodium hydroxide is an inorganic base. It participates in the oxidation of glycerol, catalyzed by Au/charcoal or Au/graphite. It also participates in solvent-free aldol condensation reaction.

Application

Sodium hydroxide may be employed for determination of specific surface area of colloidal silica, via titration. It may be employed for direct oxidation of sodium borohydride, which was investigated by cyclic and linear voltammetry, chronoamperometry and chronopotentiometry. It may be used to compose citrate buffer and borate buffers.
It may be used in the synthesis of following compounds:
  • alkylaryl amidosulfobetaines
  • (3 -[4-teroctylphenoxyethoxyethoxyethyl] dimethylammonio propane sulfonate (XOSB)
  • trisulfobetaines (TriSBn)

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

存储类别

8B - Non-combustible corrosive hazardous materials

法规信息

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Silvio Carrettin et al.
Chemical communications (Cambridge, England), (7)(7), 696-697 (2002-07-18)
Glycerol is oxidised to glyceric acid with 100% selectivity using either 1% Au/charcoal or 1% Au/graphite catalyst under mild reaction conditions (60 degrees C, 3 h, water as solvent).
M A Roberts et al.
Analytical chemistry, 69(11), 2035-2042 (1997-06-01)
This report describes a UV laser photoablation method for the production of miniaturized liquid-handling systems on polymer substrate chips. The fabrication of fluid channel and reservoir networks is accomplished by firing 200 mJ pulses from an UV excimer laser at
M Chevallet et al.
Electrophoresis, 19(11), 1901-1909 (1998-09-18)
Severe quantitative loss of protein is often observed in high-resolution two-dimensional electrophoresis of membrane proteins, while the resolution is usually not affected. To improve the solubility of proteins in this technique, we tested denaturing cocktails containing various detergents and chaotropes.

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