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Merck
CN

31107-M

氯化铵

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5%

别名:

卤砂

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关于此项目

线性分子式:
NH4Cl
化学文摘社编号:
12125-02-9
分子量:
53.49
NACRES:
NA.21
PubChem Substance ID:
329753648
eCl@ss:
38050207
UNSPSC Code:
12352300
EC Number:
235-186-4
MDL number:
MFCD00011420
Beilstein/REAXYS Number:
4371014
Assay:
≥99.5%
Form:
crystalline powder

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InChI key

NLXLAEXVIDQMFP-UHFFFAOYSA-N

InChI

1S/ClH.H3N/h1H;1H3

grade

ACS reagent, puriss. p.a.

agency

USP/NF, reag. ISO, reag. Ph. Eur.

vapor density

1.9 (vs air)

vapor pressure

1 mmHg ( 160.4 °C)

assay

≥99.5%

form

crystalline powder

impurities

acidity or alkalinity, complies, bromides and iodides, complies, ≤0.005% insoluble matter

pH

4.5-5.5 (20 °C, 5%)

mp

340 °C (subl.) (lit.)

anion traces

nitrate (NO3-): ≤5 mg/kg, phosphate (PO43-): ≤2 mg/kg, sulfate (SO42-): ≤20 mg/kg

cation traces

As: ≤0.00005%, Ca: ≤0.0005%, Cu: ≤0.0002%, Fe: ≤0.0002%, K: ≤0.005%, Mg: ≤0.0005%, Na: ≤0.005%, Ni: ≤0.0001%, Pb: ≤0.0001%, Zn: ≤0.0002%, heavy metals: ≤5 mg/kg (by ICP-OES)

suitability

complies for appearance of solution

Quality Level

100

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Application

Ammonium chloride can be used as a catalyst:
  • To synthesize 3,4-dihydropyrimidin-2-(1H)-ones via solvent-free Biginelli condensation reaction.
  • For the aldol condensation of carbonyl compounds.
  • In the thia-Michael addition reaction of thiols to different α-enones.
It can also be used as:
  • A promoter in the enantioselective hydrogenation of an unprotected β-enamine amides.
  • A pH-adjuster in the preparation of waterborne glucose silicone resin.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

存储类别

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB2393
SDBB6181
SDBB6362
SDBB4996
SDBB3330

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Identification of ammonium chloride as an effective promoter of the asymmetric hydrogenation of a beta-enamine amide
Clausen A, et al.
Organic Process Research & Development, 10, 723-726 (2006)
Physical and mechanical properties of poplar wood modified by glucose-urea-melamine resin/sodium silicate compound
Liu Q, et al.
Forests, 12, 127-127 (2021)
Ammonium chloride-catalyzed carbon-sulfur bond formation in water
Chen W, et al.
Catalysis Communications, 9, 1079-1081 (2008)
Ammonium chloride-catalyzed one-pot synthesis of 3, 4-dihydropyrimidin-2-(1H)-ones under solvent-free conditions
Shaabani A, et al.
Tetrahedron Letters, 44, 857-859 (2003)
The Vibrational Spectra of Molecules and Complex Ions in Crystals III. Ammonium Chloride and Deutero-Ammonium Chloride.
Wagner EL and Hornig DF.
J. Chem. Phys. , 18(3), 296-304 (1950)
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