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Merck
CN

31562

乙拌磷亚砜

PESTANAL®, analytical standard

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关于此项目

经验公式(希尔记法):
C8H19O3PS3
化学文摘社编号:
分子量:
290.40
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
219-679-1
Beilstein/REAXYS Number:
1712528
MDL number:
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产品名称

乙拌磷亚砜, PESTANAL®, analytical standard

InChI key

UPUGLJYNCXXUQV-UHFFFAOYSA-N

InChI

1S/C8H19O3PS3/c1-4-10-12(13,11-5-2)14-7-8-15(9)6-3/h4-8H2,1-3H3

SMILES string

CCOP(=S)(OCC)SCCS(=O)CC

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

Quality Level

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相关类别

Application

Disulfoton-sulfoxide may be used as a reference standard for the determination of the analyte:
  • In human biological samples based on QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) extraction and liquid chromatography–tandem mass spectrometry.
  • In cereal-based baby foods and wheat flour using hollow-fiber liquid-phase microextraction prior to gas chromatography with nitrogen phosphorus detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Disulfoton-sulfoxide is one of the oxidative metabolites of disulfoton, an organophosphorus insecticide used against aphids, mites, and thrips.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 1 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
农药列管产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Determination of organophosphorus pesticides and metabolites in cereal-based baby foods and wheat flour by means of ultrasound-assisted extraction and hollow-fiber liquid-phase microextraction prior to gas chromatography with nitrogen phosphorus detection.
Gonzalez-Curbelo MA, et al.
Journal of Chromatography A, 1313(6), 166-174 (2013)
Rapid determination of disulfoton and its oxidative metabolites in human whole blood and urine using QuEChERS extraction and liquid chromatography-tandem mass spectrometry.
Usui K, et al.
Legal medicine, 14(6), 309-316 (2012)
Yasuhisa Fujino et al.
Chudoku kenkyu : Chudoku Kenkyukai jun kikanshi = The Japanese journal of toxicology, 17(3), 273-277 (2004-10-22)
We encountered three cases of organophosphate poisoning treated with pralidoxime iodide (PAM) and whole-bowel irrigation without atropine sulfate. All patients recovered without persistence or recurrence of toxic symptoms and without any somatic after effects. In case 1, a 48-year-old woman
B Dementi
Journal of applied toxicology : JAT, 14(2), 119-129 (1994-03-01)
Many publications, primarily of work performed in Japan, report findings in human populations of an increased incidence of myopia and of a more advanced visual disease syndrome (Saku disease), which reportedly correlated with increasing use of organophosphate pesticides in agriculture.
Jishi Wang et al.
Journal of chromatography. A, 1521, 10-18 (2017-09-25)
In this research, the manual two-step QuEChERS approach has been streamlined and automated into a one-step method using a cleanup tube fitted within an extraction tube. A novel automatic QuEChERS combination have been developed to simplify the QuEChERS procedures and

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