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经验公式(希尔记法):
C18H25N5O5
化学文摘社编号:
分子量:
391.42
NACRES:
NA.24
UNSPSC Code:
41116107
MDL number:
Beilstein/REAXYS Number:
11330196
InChI key
JHIPUJPTQJYEQK-ZLHHXESBSA-N
SMILES string
CNC(=O)C(=N\OC)\c1ccccc1CO\N=C(C)\C(=N\OC)\C(C)=N\OC
InChI
1S/C18H25N5O5/c1-12(20-25-4)16(22-26-5)13(2)21-28-11-14-9-7-8-10-15(14)17(23-27-6)18(24)19-3/h7-10H,11H2,1-6H3,(H,19,24)/b20-12+,21-13+,22-16+,23-17+
grade
analytical standard
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
application(s)
agriculture
environmental
format
neat
Quality Level
相关类别
General description
Orysastrobin is one of the analogs of strobilurin fungicide.
Application
Orysastrobin may be used as an analytical reference standard for the determination of the analyte in:
- Rice samples by high performance liquid chromatography equipped with ultraviolet (HPLC-UV) detection and LC coupled to tandem mass spectrometry (MS/MS) with electrospray ionization (ESI) and selected reaction monitoring (SRM) detection.
- Food samples by atmospheric-pressure solids-analysis probe (ASAP) as well as desorption electrospray ionization-mass spectrometry (DESI-MS) techniques.
- Hot pepper (Capsicum annuum L.) samples by modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) method, followed by analysis using LC-MS/MS with SRM detection.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Other Notes
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Toxicological overview of a novel strobilurin fungicide, orysastrobin
van Ravenzwaay, B., et al.
Journal of Pesticide Science, 32(3), 270-277 (2007)
An assessment of atmospheric-pressure solids-analysis probes for the detection of chemicals in food.
Fussell RJ, et al.
TrAC, Trends in Analytical Chemistry, 29(11), 1326-1335 (2010)
Multiresidue method for the determination of 227 pesticides in hot pepper (Capsicum annuum L.) by liquid chromatography with tandem mass spectrometry.
Zhu YZ, et al.
Journal of Separation Science, 37(20), 2947-2954 (2014)
Desorption electrospray ionization mass spectrometry in the analysis of chemical food contaminants in food.
Nielen MWF, et al.
TrAC, Trends in Analytical Chemistry, 30(2), 165-180 (2011)
Quantitative analysis of fungicide azoxystrobin in agricultural samples with rapid, simple and reliable monoclonal immunoassay.
Watanabe E and Miyake S
Food Chemistry, 136(2), 695-702 (2013)
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