32611
氟菌唑
PESTANAL®, analytical standard
别名:
(E)-4-氯-α,α,α-三氟-N-(1-咪唑-1-基-2-丙氧基亚乙基)-邻甲苯胺, 1-{1-{[4-氯-2-(三氟甲基)苯基]亚氨基}-2-丙氧基乙基}-1H-咪唑
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关于此项目
经验公式（希尔记法）:
C15H15ClF3N3O
化学文摘社编号:
分子量:
345.75
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
41116107
MDL number:
InChI
1S/C15H15ClF3N3O/c1-2-7-23-9-14(22-6-5-20-10-22)21-13-4-3-11(16)8-12(13)15(17,18)19/h3-6,8,10H,2,7,9H2,1H3/b21-14+
SMILES string
CCCOC\C(=N/c1ccc(Cl)cc1C(F)(F)F)n2ccnc2
InChI key
HSMVPDGQOIQYSR-KGENOOAVSA-N
grade
analytical standard
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
Quality Level
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General description
Triflumizole is classified under the imidazole fungicide group of chemicals generally used for food and ornamental crop protection.
Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Triflumizole may be used as a reference standard for the determination of triflumizole in food and water samples by quick, easy, cheap, effective, rugged and safe (QuEchERS) extraction and liquid chromatography/time-of-flight mass spectrometry (LC/TOF-MS), in fruits and vegetables by gas chromatography-tandem mass spectrometry (GC-MS/MS) operating in either electron ionization (EI) or chemical ionization (CI) mode, in honeybees by acetonitrile-based extraction and GC-quadrupole MS/MS operating in multiple reaction monitoring (MRM) mode and in paddy field water by direct injection LC coupled to quadrupole-linear ion-trap MS.
Other Notes
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1B - Skin Sens. 1 - STOT RE 2
target_organs
Liver
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
农药列管产品
此项目有
Potential obesogen identified: fungicide triflumizole is associated with increased adipogenesis in mice.
Valerie J Brown
Environmental health perspectives, 120(12), A474-A474 (2012-12-06)
D Cai et al.
Se pu = Chinese journal of chromatography, 17(3), 299-300 (2003-01-29)
Triflumizole (TRI) and its metabolite [4-chloro-alpha,alpha,alpha-trifluoro-N-(1-amino-2-propoxythylidene)- O-toluidine] (MET) were extracted with methanol and reverse-extracted with dichloromethane. After evaporation to dryness, the residue in dichloromethane layer was dissolved in mobile phase for high performance liquid chromatographic determination with external standard method.
Helmut Viernstein et al.
International journal of pharmaceutics, 256(1-2), 85-94 (2003-04-16)
The solubility enhancement of biologically active compounds was analysed in dependence on temperature, amount of cosolvents and on beta-cyclodextrin as complexing agent. The analysis was performed for the systemic fungicide triflumizole (TF), a poorly water soluble compound. All parameters lead
[Determining the levels of trifumin and the products of its transformation in agricultural cultures, water and soil].
M V Pis'mennaia
Gigiena i sanitariia, (3)(3), 83-84 (1991-03-01)
Geoffrey M Calvert et al.
MMWR. Morbidity and mortality weekly report, 64(2), 42-44 (2015-01-23)
On April 10, 2014 the Washington State Department of Agriculture (WSDA) was notified by a local newspaper of a suspected pesticide poisoning incident in Douglas County involving pesticides not previously reported in the published literature to be associated with human
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