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Merck
CN

32964

苯菌酮

PESTANAL®, analytical standard

别名:

(3-溴-6-甲氧基-2-甲苯基)(2,3,4-三甲氧基-6-甲苯基)甲酮, 3′-溴-2,3,4,6′-四甲氧基-2′,6-二甲基二苯甲酮

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关于此项目

经验公式(希尔记法):
C19H21BrO5
化学文摘社编号:
分子量:
409.27
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
41116107
MDL number:
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产品名称

苯菌酮, PESTANAL®, analytical standard

InChI

1S/C19H21BrO5/c1-10-9-14(23-4)18(24-5)19(25-6)15(10)17(21)16-11(2)12(20)7-8-13(16)22-3/h7-9H,1-6H3

SMILES string

COc1ccc(Br)c(C)c1C(=O)c2c(C)cc(OC)c(OC)c2OC

InChI key

AMSPWOYQQAWRRM-UHFFFAOYSA-N

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

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Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

General description

Metrafenone is a novel benzophenone fungicide that could be used against powdery mildew and eye spot in vegetables and fruits.

Application

Metrafenone may be used as an analytical reference standard for the determination of the analyte in:
  • Vegetables by gas chromatography coupled to electron capture detector (GC-ECD).
  • Honeybees by liquid and gas chromatography combined with tandem mass spectrometry (LC-MS/MS and GC-MS/MS).
  • Animal samples and earthworms by LC-MS/MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

法规信息

农药列管产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A liquid chromatography-electrospray tandem mass spectrometry method for the determination of multiple pesticide residues involved in suspected poisoning of non-target vertebrate wildlife, livestock and pets.
Taylor MJ, et al.
Analytical Methods : Advancing Methods and Applications, 5(1), 248-259 (2013)
Anna Markheiser et al.
Insects, 11(1) (2020-01-16)
The identification of volatile organic compounds (VOCs) leading to short-range attraction and oviposition of the European grapevine moth Lobesia botrana and European grape berry moth Eupoecilia ambiguella (Lepidoptera: Tortricidae) is crucial in order to establish bait-based decision support systems for
Multi-residue method for the determination of pesticides and pesticide metabolites in honeybees by liquid and gas chromatography coupled with tandem mass spectrometry?Honeybee poisoning incidents.
Kiljanek T, et al.
Journal of Chromatography A, 1435(1), 100-114 (2016)
Determination of residual levels of metrafenone in lettuce grown under greenhouse conditions using gas chromatography with a micro-electron capture detector.
Kabir MH, et al.
Journal of Applied Biological Chemistry, 59(1), 43-49 (2016)
Débora Reis et al.
Foods (Basel, Switzerland), 9(8) (2020-07-30)
Insecticides are broadly applied in agriculture to defend crops from illnesses and pest attacks, consequently guaranteeing high production. However, their residual deposits in food products are becoming a main concern with regard to human consumption. As such, sensitive analytical methods

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