33380
4-甲基-邻-苯二胺
purum, ≥98.0% (NT)
别名:
3,4-甲苯二胺
等级
purum
质量水平
方案
≥98.0% (NT)
沸点
155-156 °C/18 mmHg (lit.)
mp
87-89 °C (lit.)
87-89 °C
应用
agriculture
environmental
SMILES字符串
Cc1ccc(N)c(N)c1
InChI
1S/C7H10N2/c1-5-2-3-6(8)7(9)4-5/h2-4H,8-9H2,1H3
InChI key
DGRGLKZMKWPMOH-UHFFFAOYSA-N
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一般描述
4-甲基-邻苯二胺是邻苯二胺的 4-取代衍生物。在酸性溶液中与亚硒酸反应生成苯并硒二唑。
应用
4-甲基邻苯二胺在硒（IV）的分光光度测定中用作显色试剂。它用于通过与脱氢乙酸和水杨醛缩合合成不对称四齿席夫碱。
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Spectrophotometric determination of selenium (IV) with 4-methyl-o-phenylenediamine based on piazselenol formation.
Kartal S, et al.
Journal of Analytical Chemistry, 65(12), 1221-1227 (2010)
Some 4-substituted< i> o</i>-phenylenediamines as reagents for selenium.
Tanaka M and Kawashima T.
Talanta, 12(3), 211-219 (1965)
Synthesis, characterization and thermal study of some transition metal complexes of an asymmetrical tetradentate Schiff base ligand.
Munde AS, et al.
J. Serb. Chem. Soc., 75(3), 349-359 (2010)
T A Marks et al.
Teratology, 24(3), 253-265 (1981-12-01)
Pregnant outbred albino (CD-1) mice were given 2-nitro-p-phenylenediamine (2NPPD; 32-256 mg/kg/day), 4-nitro-o-phenylenediamine (4NOPD; 16-1024 mg/kg/day) or 2,5-toluenediamine sulfate (2,5TDS; 16-64 mg/kg/day) by subcutaneous injection on Days 6-15 of gestation. The mice were killed on Day 18, the general health and
Effect of 4 toluene diamine isomers on murine testicular DNA synthesis.
E J Greene et al.
Mutation research, 91(1), 75-79 (1981-01-01)
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