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经验公式(希尔记法):
C8H8BrCl2O3PS
化学文摘社编号:
分子量:
366.00
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
218-277-3
Beilstein/REAXYS Number:
1988276
MDL number:
产品名称
甲基-溴硫磷, PESTANAL®, analytical standard
InChI key
NYQDCVLCJXRDSK-UHFFFAOYSA-N
InChI
1S/C8H8BrCl2O3PS/c1-12-15(16,13-2)14-8-4-6(10)5(9)3-7(8)11/h3-4H,1-2H3
SMILES string
COP(=S)(OC)Oc1cc(Cl)c(Br)cc1Cl
grade
analytical standard
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable
mp
53-56 °C
suitability
passes test for identity (NMR)
application(s)
agriculture
environmental
format
neat
storage temp.
2-8°C
Quality Level
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Application
Bromophos-methyl may be used as a reference standard for the determination of bromophos-methyl in biological samples using headspace solid-phase microextraction and gas chromatography with mass spectrometric detection.
Bromophos-methyl may be used as a reference standard for the determination of the insecticidel in berries using head-space solid phase microextraction with gas chromatography coupled to mass spectrometry (SPME-GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
General description
Bromophos-methyl is an organophosphorus insecticide widely used to control a wide variety of insects in agriculture and forestry sector.
Other Notes
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
农药列管产品
此项目有
Simple determination of 22 organophosphorous pesticides in human blood using headspace solid-phase microextraction and gas chromatography with mass spectrometric detection.
Musshoff F, et al.
Journal of Chromatographic Science, 40(1), 29-39 (2002)
An analytical method for the rapid screening of organophosphate pesticides in human biological samples and foodstuffs.
Tarbah AF, et al.
Forensic Science International, 121(1-2), 126-133 (2001)
Headspace solid-phase microextraction in combination with gas chromatography-mass spectrometry for the rapid screening of organophosphorus insecticide residues in strawberries and cherries.
Lambropoulou AD and Albanis AT
Journal of Chromatography A, 993(1-2), 197-203 (2003)
[Determination of bromofos, diazinon and methylpyrimifos in fruit and vegetables].
J Zadrozińska
Roczniki Panstwowego Zakladu Higieny, 28(1), 69-78 (1977-01-01)
P Santhoshkumar et al.
Neurotoxicology and teratology, 16(3), 227-232 (1994-05-01)
Bromophos, an organophosphorus compound, is known to cross the placental barrier. The response of the foetal brain acetylcholinesterase (AChE) to in vivo Bromophos exposure is not known. This study measured the in vivo time-course of cholinesterase (ChE) inhibition and recovery
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