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Merck
CN

33400

甲基-溴硫磷

PESTANAL®, analytical standard

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关于此项目

经验公式(希尔记法):
C8H8BrCl2O3PS
化学文摘社编号:
分子量:
366.00
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
218-277-3
Beilstein/REAXYS Number:
1988276
MDL number:
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产品名称

甲基-溴硫磷, PESTANAL®, analytical standard

InChI key

NYQDCVLCJXRDSK-UHFFFAOYSA-N

InChI

1S/C8H8BrCl2O3PS/c1-12-15(16,13-2)14-8-4-6(10)5(9)3-7(8)11/h3-4H,1-2H3

SMILES string

COP(=S)(OC)Oc1cc(Cl)c(Br)cc1Cl

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

mp

53-56 °C

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

Quality Level

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Application

Bromophos-methyl may be used as a reference standard for the determination of bromophos-methyl in biological samples using headspace solid-phase microextraction and gas chromatography with mass spectrometric detection.
Bromophos-methyl may be used as a reference standard for the determination of the insecticidel in berries using head-space solid phase microextraction with gas chromatography coupled to mass spectrometry (SPME-GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Bromophos-methyl is an organophosphorus insecticide widely used to control a wide variety of insects in agriculture and forestry sector.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

农药列管产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Simple determination of 22 organophosphorous pesticides in human blood using headspace solid-phase microextraction and gas chromatography with mass spectrometric detection.
Musshoff F, et al.
Journal of Chromatographic Science, 40(1), 29-39 (2002)
An analytical method for the rapid screening of organophosphate pesticides in human biological samples and foodstuffs.
Tarbah AF, et al.
Forensic Science International, 121(1-2), 126-133 (2001)
Headspace solid-phase microextraction in combination with gas chromatography-mass spectrometry for the rapid screening of organophosphorus insecticide residues in strawberries and cherries.
Lambropoulou AD and Albanis AT
Journal of Chromatography A, 993(1-2), 197-203 (2003)
[Determination of bromofos, diazinon and methylpyrimifos in fruit and vegetables].
J Zadrozińska
Roczniki Panstwowego Zakladu Higieny, 28(1), 69-78 (1977-01-01)
P Santhoshkumar et al.
Neurotoxicology and teratology, 16(3), 227-232 (1994-05-01)
Bromophos, an organophosphorus compound, is known to cross the placental barrier. The response of the foetal brain acetylcholinesterase (AChE) to in vivo Bromophos exposure is not known. This study measured the in vivo time-course of cholinesterase (ChE) inhibition and recovery

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