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Merck
CN

33658

啶氧菌酯

PESTANAL®, analytical standard

别名:

(E)-α-甲氧基亚甲基-2-(3-三氟甲基-2-吡啶氧甲基)乙酸苯甲酯

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关于此项目

经验公式(希尔记法):
C18H16F3NO4
化学文摘社编号:
分子量:
367.32
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
41116107
MDL number:
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InChI

1S/C18H16F3NO4/c1-24-11-14(17(23)25-2)13-7-4-3-6-12(13)10-26-16-9-5-8-15(22-16)18(19,20)21/h3-9,11H,10H2,1-2H3/b14-11-

SMILES string

CO\C=C(/C(=O)OC)c1ccccc1COc2cccc(n2)C(F)(F)F

InChI key

IBSNKSODLGJUMQ-KAMYIIQDSA-N

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

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General description

Picoxystrobin is classified under the strobulins family of fungicides that exhibit broad range activity against plant pathogenspathogenic fungi.

Application

Picoxystrobin may be used as a reference standard for the determination of picoxystrobin in:
  • Honeybees using acetonitrile-based extraction followed by dispersive solid-phase extraction (d-SPE) cleanup and gas chromatography−tandem quadrupole mass spectrometry (GC−MS/MS).
  • Foodstuffs by liquid chromatography (LC) combined with MS/MS, atmospheric pressure chemical ionization (APCI) and electrospray ionization (ESI).
  • Paddy field water by direct injection using LC coupled with quadrupole-linear ion trap (QqLIT)-MS.
  • Maize by acetonitrile-based extraction with dispersive liquid−liquid microextraction (DLLME) followed by GC-MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves

法规信息

农药列管产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Honglei Zhao et al.
Journal of the science of food and agriculture, 100(14), 5145-5151 (2020-06-11)
Pyraclostrobin and picoxystrobin are two representative pesticides of strobilurins used to treat cucumber downy mildew, which have raised issues of food safety and human health. A new formulation containing these two compounds is being prepared for marketing in China. The
Xinzhong Zhang et al.
Journal of the science of food and agriculture, 101(1), 194-204 (2020-07-06)
Picoxystrobin is a new osmotic and systemic broad-spectrum methoxyacrylate fungicide with a good control effect on tea anthracnose, so it has been proposed to spray picoxystrobin before the occurrence and onset of tea anthracnose during tea bud growth in order
Yabing Duan et al.
Pesticide biochemistry and physiology, 153, 95-105 (2019-02-13)
Target leaf spot caused by Corynespora cassiicola is an economically important foliar disease on cucumber. In recent years, this disease has caused a serious problem on greenhouse-cultivated cucumber in China. In this study, to explore the characteristics and possible causes
Marianne Stenrød et al.
PloS one, 8(6), e66989-e66989 (2013-07-03)
There is widespread use of chemical amendments to meet the demands for increased productivity in agriculture. Potentially toxic compounds, single or in mixtures, are added to the soil medium on a regular basis, while the ecotoxicological risk assessment procedures mainly
Stir bar sorptive extraction coupled to liquid chromatography for the analysis of strobilurin fungicides in fruit samples
Campillo N, et al.
Journal of Chromatography A, 1217(27), 4529-4534 (2010)

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