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Merck
CN

33683

BDE No 153 溶液

50 μg/mL in isooctane, analytical standard

别名:

2,2′,4,4′,5,5′-六溴二苯醚 溶液, 2,2′,4,4′,5,5′-HexaBDE, PBDE 153

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关于此项目

经验公式(希尔记法):
C12H4Br6O
化学文摘社编号:
分子量:
643.58
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
41116107
EC Number:
208-759-1
MDL number:
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InChI key

RZXIRSKYBISPGF-UHFFFAOYSA-N

InChI

1S/C12H4Br6O/c13-5-1-9(17)11(3-7(5)15)19-12-4-8(16)6(14)2-10(12)18/h1-4H

SMILES string

Brc1cc(Br)c(Oc2cc(Br)c(Br)cc2Br)cc1Br

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

concentration

50 μg/mL in isooctane

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

environmental

format

single component solution

storage temp.

2-8°C

Quality Level

Application

BDE No 153 may be used as an analytical reference standard for the determination of the analyte in:
  • House dust samples using isotope dilution method combined with liquid chromatography coupled to negative ionization atmospheric pressure photoionization tandem mass spectrometry (LC-NI-APPI-MS/MS).
  • Adipose tissue samples using gas chromatography coupled to ion-trap mass spectrometry (GC-IT-MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

BDE No 153 is a contaminant, which can also be commercially used as a flame retardant additive in building materials, textiles, plastics, and electronic equipment.

Other Notes

The customer needs to make sure that the standard is homogeneous, this can be achieved by shaking, vortexing , or sonicating the ampoule before opening the ampoule. Care should be taken when opening the ampoule to avoid any injuries from the broken glass.
The standard should be transferred to a clean and appropriate vial or flask using clean pipettes or micro pipettes. The vial should be immediately capped to avoid any loss or evaporation of the solvent.
After opening the ampoule, the standard should not be stored or kept in the ampoule. To preserve the integrity of the product, the standard should be transferred to an appropriate vial that must be capped and stored according to the recommendation on the Certificate of Analysis.

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

10.4 °F

flash_point_c

-12 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

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E Beristain-Montiel et al.
Journal of chromatography. A, 1477, 100-107 (2016-11-30)
New clean technologies are needed to determine concentration of organic pollutants without generating more pollution. A method to extract Persistent Organic Pollutants (POPs) from airborne particulate matter was developed using a novel technology recently patented called ultrasound assisted extraction micro-scale
Youssef Oulhote et al.
Environment international, 119, 79-88 (2018-06-26)
Prenatal exposure to polybrominated diphenyl ethers (PBDEs) has been associated with cognitive deficits and behavioral problems in children. To date, no study has examined this exposure in association with neurobehavioral development in infants younger than 12 months assessed with observational tasks.
Development of a gas chromatography/ion trap mass spectrometry based method for the quantification of polybrominated diphenyl ethers and polychlorinated biphenyls in adipose tissue.
Naert C, et al.
Rapid Communications in Mass Spectrometry, 18(19), 2317-2332 (2004)
Isotope dilution method for determination of polybrominated diphenyl ethers using liquid chromatography coupled to negative ionization atmospheric pressure photoionization tandem mass spectrometry: validation and application to house dust.
Abdallah E-A M, et al.
Analytical Chemistry, 81(17), 7460-7469 (2009)
Siqi Zhang et al.
Neurotoxicology and teratology, 73, 54-66 (2019-04-04)
Asexual freshwater planarians are an attractive invertebrate model for high-throughput neurotoxicity screening, because they possess multiple quantifiable behaviors to assess distinct neuronal functions. Planarians uniquely allow direct comparisons between developing and adult animals to distinguish developmentally selective effects from general

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