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Merck
CN

339075

硼酸酐

99.98% trace metals basis

别名:

三氧化二硼

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关于此项目

经验公式(希尔记法):
B2O3
化学文摘社编号:
分子量:
69.62
PubChem Substance ID:
eCl@ss:
38120103
UNSPSC Code:
12352300
NACRES:
NA.21
EC Number:
215-125-8
MDL number:
Assay:
99.98% trace metals basis
Form:
powder
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InChI key

JKWMSGQKBLHBQQ-UHFFFAOYSA-N

InChI

1S/B2O3/c3-1-5-2-4

SMILES string

O=BOB=O

vapor density

>1 (vs air)

description

for inorganic trace analysis

assay

99.98% trace metals basis

form

powder

mp

450 °C (lit.)

density

2.46 g/mL at 25 °C (lit.)

Quality Level

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Application

在使用三乙基硅烷和三氟化硼将酮选择性还原成烃的过程中,硫酸中的硼酸酐可用作洗涤剂以除去形成的副产物氟化氢气体。与羟基磷灰石结合,它可用于催化气相贝克曼重排过程,形成尼龙-6。

pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

Repr. 1B

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

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Fry JL, et al.
Organic Syntheses, 60, 108-108 (1981)
Vapor-phase Beckmann rearrangement of cyclohexanone oxime over boria-hydroxyapatite catalyst
Izumi Y, et al.
Chemistry Letters (Jpn), 12(10), 1649-1652 (1983)
Pratik Koirala et al.
The journal of physical chemistry. A, 117(6), 1310-1318 (2012-11-03)
Using density functional theory based calculations, we have systematically studied the equilibrium geometries, relative stabilities, and electronic and magnetic properties of Fe and Mn atoms interacting with a varying number of BO(2) moieties. These clusters are found to exhibit hyperhalogen
Roger F Brown et al.
Journal of biomedical materials research. Part A, 88(2), 392-400 (2008-02-29)
Glasses containing varying amounts of B(2)O(3) were prepared by partially or fully replacing the SiO(2) in silicate 45S5 bioactive glass with B(2)O(3). The effects of the B(2)O(3) content of the glass on its conversion to hydroxyapatite (HA) and on the
Xiaofeng Liu et al.
Chemical communications (Cambridge, England), (27)(27), 4073-4075 (2009-07-02)
A facile strategy based on the reaction of urea and boric acid is developed for the synthesis of toxicity-free BCNO nanocrystals containing carbon impurities and which exhibit efficient multi-color fluorescence under both single-photon and two-photon excitation.

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