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Merck
CN

34854-M

氯仿

suitable for HPLC, ≥99.8%, amylene stabilized

别名:

三氯甲烷

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经验公式(希尔记法):
CHCl3
化学文摘社编号:
分子量:
119.38
UNSPSC Code:
12190000
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-663-8
Beilstein/REAXYS Number:
1731042
MDL number:
Assay:
≥99.8%
Grade:
HPLC grade
Technique(s):
HPLC: suitable
Vapor pressure:
160 mmHg ( 20 °C)
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InChI key

HEDRZPFGACZZDS-UHFFFAOYSA-N

InChI

1S/CHCl3/c2-1(3)4/h1H

SMILES string

ClC(Cl)Cl

grade

HPLC grade

vapor density

4.1 (vs air)

vapor pressure

160 mmHg ( 20 °C)

assay

≥99.8%

form

liquid

quality

amylene stabilized

technique(s)

HPLC: suitable

impurities

Free acid, in accordance, acetone, aldehyde, in accordance (nessler test), free chlorine (Cl), in accordance, ≤0.0005% non-volatile matter, ≤0.001% free acid (as HCl), <0.01% water (Karl Fischer)

evapn. residue

≤0.0005%

color

APHA: ≤10

transmittance

250 nm, ≥50%, 260 nm, ≥85%, 280 nm, ≥99%

mp

−63 °C (lit.)

solubility

water: soluble (8.7 g/l at 23 °C (73 °F) - OECD Test Guideline 105)

density

1.48 g/mL at 25 °C

anion traces

chloride (Cl-): in accordance

cation traces

Pb: ≤0.05 mg/kg

absorption

in accordance

λ

H2O reference

UV absorption

λ: 250 nm Amax: ≤1.00, λ: 260 nm Amax: ≤0.30, λ: 280 nm Amax: ≤0.005

suitability

passes test for reaction against H2SO4, passes test for suitability of determ. w. dithizone

application(s)

general analytical

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General description

Chloroform, a halogenated hydrocarbon, is widely employed as a solvent. Its photochemical degradation has been investigated in the presence of TiO2 aqueous suspensions (wavelength range of 310-380nm).

Application

Chloroform has been employed for the ion exchange isolation of sulfatides from the urinary samples by using DEAE-cellulose membranes before the tandem mass spectrometric analysis. It has been used as a solvent for the Langmuir-Blodgett (LB) deposition of lipid bilayers over mica sheets (silver coated back).†

Other Notes

Important notice
  • The article number 34854-4X2.5L-M will be discontinued. Please order the single bottle 34854-2.5L-M which is physically identical with the same exact specifications.
  • The article number 34854-6X1L-M will be discontinued. Please order the single bottle 34854-1L-M which is physically identical with the same exact specifications.
Discover LiChropur reagents ideal for HPLC or LC-MS analysis

pictograms

Skull and crossbonesHealth hazard

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 - STOT SE 3

target_organs

Central nervous system

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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Ladislav Kuchař et al.
Clinica chimica acta; international journal of clinical chemistry, 425, 153-159 (2013-07-11)
Prediagnostic steps in suspected metachromatic leukodystrophy (MLD) rely on clinical chemical methods other than enzyme assays. We report a new diagnostic method which evaluates changes in the spectrum of molecular types of sulfatides (3-O-sulfogalactosyl ceramides) in MLD urine. The procedure

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