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Merck
CN

35620

2,6-二氯醌-4-氯亚胺

for spectrophotometric det. of vitamin B6, ≥99.0%

别名:

2,6-二氯苯醌氯亚胺, Gibb 试剂

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关于此项目

经验公式(希尔记法):
C6H2Cl3NO
化学文摘社编号:
分子量:
210.45
UNSPSC Code:
41116105
NACRES:
NA.21
PubChem Substance ID:
EC Number:
202-937-2
Beilstein/REAXYS Number:
2364249
MDL number:
Assay:
≥99.0% (AT), ≥99.0%
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Quality Level

assay

≥99.0% (AT), ≥99.0%

quality

for spectrophotometric det. of vitamin B6

technique(s)

UV/Vis spectroscopy: suitable

mp

65-67 °C (lit.), 65-68 °C

application(s)

food and beverages
vitamins, nutraceuticals, and natural products

storage temp.

2-8°C

SMILES string

Cl\N=C1\C=C(Cl)C(=O)C(Cl)=C1

InChI

1S/C6H2Cl3NO/c7-4-1-3(10-9)2-5(8)6(4)11/h1-2H

InChI key

YHUMTHWQGWPJOQ-UHFFFAOYSA-N

General description

2,6-Dichloroquinone-4-chloroimide generally find application in being used as spot test and chromatographic spray reagents, mainly for phenols, though it can be used in detection of other types of compounds such as antioxidants, few primary and secondary amines, on silica gel chromatographic plates. Its decomposition rate is directly proportional to pressure.

Application

Gibb′s reagent was used in paper chromatography, in an experiment conducted to semi-quantitatively estimate tyramine and octopamine.


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pictograms

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signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Self-react. C - Skin Irrit. 2

存储类别

4.1A - Other explosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Colour reaction of phenols with the gibbs reagent. The reaction mechanism and decomposition and stabilisation of the reagent.
Svobodova D
Microchimica Acta, 67 (3-4), 251-264 (1977)
Occurrence and some properties of eledoisin in extracts of posterior salivary glands of Eledone.
Anastasi A and Erspamer V.
British Journal of Pharmacology and Chemotherapy, 19 (2), 326-336 (1962)
2, 6-Dichloroquinone 4-chloroimide as a reagent for amines and aromatic hydrocarbons on thin-layer chromatograms.
Hansbro RJ
Analytical Chemistry, 40 (14), 2138-2143 (1968)



全球贸易项目编号

货号GTIN
35620-10G04061831812329
35620-50G04061831812336