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经验公式(希尔记法):
C10H10N4O
化学文摘社编号:
分子量:
202.21
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
255-349-3
Beilstein/REAXYS Number:
613129
MDL number:
产品名称
苯嗪草酮, PESTANAL®, analytical standard
InChI key
VHCNQEUWZYOAEV-UHFFFAOYSA-N
InChI
1S/C10H10N4O/c1-7-12-13-9(10(15)14(7)11)8-5-3-2-4-6-8/h2-6H,11H2,1H3
SMILES string
CC1=NN=C(c2ccccc2)C(=O)N1N
grade
analytical standard
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable
impurities
≤0.5% water (Karl Fischer)
mp
165-170 °C
suitability
passes test for identity (NMR)
application(s)
agriculture
environmental
format
neat
Quality Level
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Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
General description
Metamitron is a 1,2,4-triazine herbicide, which is yellow crystalline in nature and can easily degrade in soil to form stable metabolites. It can be prepared via reaction of N-acetyl-benzylhydrazone with hydroxylamine in the presence of potassium hydroxide in pyridine.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
农药列管产品
此项目有
The Pesticide Encyclopedia (2014)
Adsorption of 1, 2, 4-triazine pesticides metamitron and metribuzin on lignin
Ludvik J and Zuman P
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 64, 15-20 (2000)
E Mechant et al.
Communications in agricultural and applied biological sciences, 75(2), 53-59 (2010-01-01)
Chenopodium album L. (fat-hen) with a Ser264-Gly mutation is resistant to photosystem II-inhibiting herbicides like the triazinone metamitron, a key herbicide in sugar beet. In recent years, this resistant biotype may cause unsatisfactory weed control in Belgian sugar beet. However
Jirí Ludvík et al.
Acta crystallographica. Section C, Crystal structure communications, 63(Pt 4), o259-o262 (2007-04-07)
The title structures, both C(10)H(10)N(4)O, are substitutional isomers. The N-N bond lengths are longer and the C=N bond lengths are shorter by ca 0.025 A than the respective average values in the C=N-N=C group of asymmetric triazines; the assessed respective
T De Marez et al.
Communications in agricultural and applied biological sciences, 72(2), 265-269 (2008-04-11)
Seeds of various fat-hen populations (Chenopodium album L.), mostly originating from sugar beet fields, were subjected to treatments with the following herbicides: metamitron, acetochlor, dimethenamid-P and S-metolachlor. Herbicides were applied either incorporated into a sandy Loam soil (2005-2007) and/or on
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