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Merck
CN

36546

氯乙酸甲酯

PESTANAL®, analytical standard

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线性分子式:
ClCH2COOCH3
化学文摘社编号:
分子量:
108.52
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
202-501-1
Beilstein/REAXYS Number:
506255
MDL number:
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InChI key

QABLOFMHHSOFRJ-UHFFFAOYSA-N

InChI

1S/C3H5ClO2/c1-6-3(5)2-4/h2H2,1H3

SMILES string

COC(=O)CCl

grade

analytical standard

vapor density

3.8 (vs air)

vapor pressure

10 mmHg ( 25 °C), 5.25 mmHg ( 20 °C)

product line

PESTANAL®

autoignition temp.

869 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

18.5 %

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

Quality Level

bp

130 °C/740 mmHg (lit.)

mp

−33 °C (lit.)

density

1.238 g/mL at 25 °C (lit.)

application(s)

agriculture
environmental

format

neat

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Application

Methyl chloroacetate can find applications as a solvent in the liquid-liquid extraction of neutral compounds like alkylphenones, separated using micellar electrokinetic chromatography.
Methyl chloroacetate can find applications as a solvent in the liquid-liquid extraction of neutral compounds like alkylphenones, separated using micellar electrokinetic chromatography.Methyl chloroacetate may be used as a precursor for the synthesis of d3-labeled dimethoate, an internal standard used for the quantification of dimethoate in food samples using isotope dilution and liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) with multiple reaction monitoring mode (MRM).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

116.6 °F - closed cup

flash_point_c

47 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Methyl chloroacetate as an extraction solvent for coupling liquid?liquid semimicroextraction with micellar electrokinetic chromatography through on-capillary decomposition for the separation of neutral compounds with concentration enhancement
Wang T, et al.
Journal of Chromatography A, 1147, 105-110 (2007)
Screening of dimethoate in food by isotope dilution and electrospray ionization tandem mass spectrometry
Mazzotti F, et al.
Rapid Communications in Mass Spectrometry, 23(10), 1515-1518 (2009)

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