36546
氯乙酸甲酯
PESTANAL®, analytical standard
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关于此项目
线性分子式:
ClCH2COOCH3
化学文摘社编号:
分子量:
108.52
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
202-501-1
Beilstein/REAXYS Number:
506255
MDL number:
InChI key
QABLOFMHHSOFRJ-UHFFFAOYSA-N
InChI
1S/C3H5ClO2/c1-6-3(5)2-4/h2H2,1H3
SMILES string
COC(=O)CCl
grade
analytical standard
vapor density
3.8 (vs air)
vapor pressure
10 mmHg ( 25 °C), 5.25 mmHg ( 20 °C)
product line
PESTANAL®
autoignition temp.
869 °F
shelf life
limited shelf life, expiry date on the label
expl. lim.
18.5 %
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
Quality Level
bp
130 °C/740 mmHg (lit.)
mp
−33 °C (lit.)
density
1.238 g/mL at 25 °C (lit.)
application(s)
agriculture
environmental
format
neat
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Application
Methyl chloroacetate can find applications as a solvent in the liquid-liquid extraction of neutral compounds like alkylphenones, separated using micellar electrokinetic chromatography.
Methyl chloroacetate can find applications as a solvent in the liquid-liquid extraction of neutral compounds like alkylphenones, separated using micellar electrokinetic chromatography.Methyl chloroacetate may be used as a precursor for the synthesis of d3-labeled dimethoate, an internal standard used for the quantification of dimethoate in food samples using isotope dilution and liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) with multiple reaction monitoring mode (MRM).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
116.6 °F - closed cup
flash_point_c
47 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Methyl chloroacetate as an extraction solvent for coupling liquid?liquid semimicroextraction with micellar electrokinetic chromatography through on-capillary decomposition for the separation of neutral compounds with concentration enhancement
Wang T, et al.
Journal of Chromatography A, 1147, 105-110 (2007)
Screening of dimethoate in food by isotope dilution and electrospray ionization tandem mass spectrometry
Mazzotti F, et al.
Rapid Communications in Mass Spectrometry, 23(10), 1515-1518 (2009)
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