36546
氯乙酸甲酯
PESTANAL®, analytical standard
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线性分子式:
ClCH2COOCH3
化学文摘社编号:
分子量:
108.52
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
202-501-1
Beilstein/REAXYS Number:
506255
MDL number:
InChI key
QABLOFMHHSOFRJ-UHFFFAOYSA-N
InChI
1S/C3H5ClO2/c1-6-3(5)2-4/h2H2,1H3
SMILES string
COC(=O)CCl
grade
analytical standard
vapor density
3.8 (vs air)
vapor pressure
10 mmHg ( 25 °C), 5.25 mmHg ( 20 °C)
product line
PESTANAL®
autoignition temp.
869 °F
shelf life
limited shelf life, expiry date on the label
expl. lim.
18.5 %
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
Quality Level
bp
130 °C/740 mmHg (lit.)
mp
−33 °C (lit.)
density
1.238 g/mL at 25 °C (lit.)
application(s)
agriculture
environmental
format
neat
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Application
Methyl chloroacetate can find applications as a solvent in the liquid-liquid extraction of neutral compounds like alkylphenones, separated using micellar electrokinetic chromatography.
Methyl chloroacetate can find applications as a solvent in the liquid-liquid extraction of neutral compounds like alkylphenones, separated using micellar electrokinetic chromatography.Methyl chloroacetate may be used as a precursor for the synthesis of d3-labeled dimethoate, an internal standard used for the quantification of dimethoate in food samples using isotope dilution and liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS) with multiple reaction monitoring mode (MRM).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
116.6 °F - closed cup
flash_point_c
47 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Screening of dimethoate in food by isotope dilution and electrospray ionization tandem mass spectrometry
Mazzotti F, et al.
Rapid Communications in Mass Spectrometry, 23(10), 1515-1518 (2009)
Methyl chloroacetate as an extraction solvent for coupling liquid?liquid semimicroextraction with micellar electrokinetic chromatography through on-capillary decomposition for the separation of neutral compounds with concentration enhancement
Wang T, et al.
Journal of Chromatography A, 1147, 105-110 (2007)
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