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Merck
CN

36691

Sigma-Aldrich

二聚环戊二烯

purum, ≥95.0% (GC)

别名:

4,7-亚甲基-3a,4,7,7a-四氢茚, DCPD, 环戊二烯二聚体

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关于此项目

经验公式(希尔记法):
C10H12
化学文摘社编号:
分子量:
132.20
Beilstein:
1904092
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
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等级

purum

方案

≥95.0% (GC)

包含

~0.05% 2,6-di-tert.-butyl-4-methylphenol as stabilizer

折射率

n20/D 1.511

沸点

170 °C (lit.)

mp

33 °C (lit.)

密度

0.986 g/mL at 25 °C (lit.)

SMILES字符串

C1C=CC2C3CC(C=C3)C12

InChI

1S/C10H12/c1-2-9-7-4-5-8(6-7)10(9)3-1/h1-2,4-5,7-10H,3,6H2/t7-,8+,9?,10?/m0/s1

InChI key

HECLRDQVFMWTQS-AFWXGSBKSA-N

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其他说明

环戊二烯的制备

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

89.6 °F - closed cup

闪点(°C)

32 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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R.B. Moffett
Organic Syntheses, IV, 238-238 (1963)
S E Barnes et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(13-14), 2946-2952 (2005-09-17)
The cure of polydicyclopentadiene conducted by ring-opening metathesis polymerisation in the presence of a Grubbs catalyst was studied using non-invasive Raman spectroscopy. The spectra of the monomer precursor and polymerised product were fully characterised and all stages of polymerisation monitored.
L G Stehmeier et al.
Biodegradation, 10(2), 135-148 (1999-08-31)
Dicyclopentadiene (DCPD) is formed during the pyrolysis of alkanes to produce olefins suitable for manufacturing synthetic polymers. DCPD has an irritating odor with a 5 ppb detection level that provides the impetus for remediation efforts. One method of destroying odors
Abhinaba Gupta et al.
Chemical communications (Cambridge, England), 47(37), 10236-10238 (2011-08-23)
Thimbles composed of polydicyclopentadiene retained Pd and phosphines used in Buchwald-Hartwig and Sonogashira coupling reactions but allowed the products to permeate. The products were isolated in high yields on the exteriors of the thimbles with no detectable contamination from phosphine
Metal-mediated retro Diels-Alder of dicyclopentadiene derivatives: a convenient synthesis of [(Cp-R)M(CO)3] (M = 99mTc, Re) complexes.
Yu Liu et al.
Journal of the American Chemical Society, 130(5), 1554-1555 (2008-01-12)

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