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Merck
CN

36849

噁唑禾草灵

PESTANAL®, analytical standard

别名:

2-{4-[(6-氯苯并噁唑-2-基)氧]苯氧基}丙酸

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关于此项目

经验公式(希尔记法):
C16H12ClNO5
化学文摘社编号:
分子量:
333.72
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
8395406
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grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CC(Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1)C(O)=O

InChI

1S/C16H12ClNO5/c1-9(15(19)20)21-11-3-5-12(6-4-11)22-16-18-13-7-2-10(17)8-14(13)23-16/h2-9H,1H3,(H,19,20)

InChI key

MPPOHAUSNPTFAJ-UHFFFAOYSA-N

General description

Fenoxaprop is the chiral metabolite formed due to the degradation of its parent compound – Fenoxaprop-ethyl, in soil. Fenoxaprop belongs to the group of aryloxyphenoxypropionate (APP) herbicides and has been used widely for the selective postemergence control of annual and perennial grass weeds in broadleaf crops. This systemic herbicide is primarily absorbed by leaves, translocated both acropetally and basipetally in the phloem and xylem to roots or rhizomes. Fenoxaprop acts by inhibiting acetyl CoA carboxylase (ACCase) – a key enzyme in lipid biosynthesis and blocks the production of phospholipids used in building new membranes.

According to Commission Regulation (1107/2009), fenoxaprop is not approved for use as a plant protection product in the European Union. However, a default MRL of 0.01 mg/kg is set according to Art 18(1)(b) Reg 396 / 2005.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support. The analytical standard (Pestanal) can be used to:

  • Develop an HPLC method for the determination of fenoxaprop-ethyl and fenoxaprop residues in four soil types using two extraction procedures
  • Validate the resistance of fenoxaprop in wild oats in Turkey and investigate cross and multiple resistance patterns of fenoxaprop-resistant wild oat populations
  • Investigate the degradation of fenoxaprop-ethyl and fenoxaprop in three soils were under native and sterilized conditions using enantioselective high-performance liquid chromatography (HPLC)
  • Determine the effect of soil moisture, temperature, and light intensity on the spray deposition of fenoxaprop and imazamethabenz applied to wild oat plants
  • Investigate and quantify the resistance of Japanese foxtail (Alopecurus japonicus) to fenoxaprop and pinoxaden in China and elucidate the basis of resistance to these herbicides

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany


pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

存储类别

11 - Combustible Solids

wgk

WGK 3

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

农药列管产品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Susana Meseguer-Lloret et al.
Applied spectroscopy, 70(2), 312-321 (2016-02-24)
Two new chemiluminescence (CL) methods are described for the determination of the herbicide 4-(4-chloro-o-tolyloxy) butyric acid (MCPB). First, a flow injection chemiluminescence (FI-CL) method is proposed. In this method, MCPB is photodegraded with an ultraviolet (UV) lamp and the photoproducts
Shizuka Saito-Shida et al.
Analytical methods : advancing methods and applications, 13(7), 894-902 (2021-01-26)
A reliable multiresidue method was developed for determining multiclass acidic pesticides in cereal grains, legumes, vegetables, and fruits. The target pesticides comprise 75 compounds, including phenoxy acid, sulfonylurea, imidazoline, and triazolopyrimidine herbicides, with acidic dissociation constant (pKa) values of 1.9-5.9.
Giovanni D'Orazio et al.
Journal of chromatography. A, 1623, 461213-461213 (2020-06-09)
In the present study separation of enantiomers of some chiral neutral, basic and weakly acidic analytes was investigated on the chiral stationary phase (CSP) made by covalent immobilization of amylose tris(3-chloro-5-methylphenylcarbamate) onto aminopropylsilanized (APS) silica in nano-liquid chromatography (nano-LC) in



全球贸易项目编号

货号GTIN
850540P-1G04061835191178
36849-100MG-R04061831832846