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Merck
CN

40252

N,N-二甲基甲酰胺二乙缩醛

for esterification of fatty acids, ≥95.0% (GC)

别名:

1,1-二乙氧基-N,N-二甲基甲胺, 1,1-二乙氧基三甲胺

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关于此项目

线性分子式:
(CH3)2NCH(OC2H5)2
化学文摘社编号:
分子量:
147.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-707-9
Beilstein/REAXYS Number:
741889
MDL number:
Assay:
≥95.0% (GC)
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Quality Level

assay

≥95.0% (GC)

quality

for esterification of fatty acids

color

colorless to yellow

refractive index

n20/D 1.397-1.401, n20/D 1.400 (lit.)

bp

130-133 °C (lit.)

density

0.859 g/mL at 25 °C (lit.)

functional group

amine, ether

SMILES string

CCOC(OCC)N(C)C

InChI

1S/C7H17NO2/c1-5-9-7(8(3)4)10-6-2/h7H,5-6H2,1-4H3

InChI key

BWKAYBPLDRWMCJ-UHFFFAOYSA-N

General description

N,N-Dimethylformamide diethyl acetal (DMF diethyl acetal) on reaction with butanol affords N,N-dimethylformamide dibutyl acetal. It participates in various alkylation, formylation, and aminomethylenation reactions. It has been synthesized from N,N-dialkyl(chloromethylene)ammonium chloride.
N,N-Dimethylformamide diethyl acetal undergoes Me3SiCl-mediated three-component coupling reaction with alkyne to yield 2,3,4,5-tetrasubstituted pyridine derivatives.

Application

N,N-Dimethylformamide diethyl acetal is a suitable reagent for the esterification of fatty acids. It is suitable reagent used in the quantification of cocaine and its primary metabolite, benzoyl ecgonine, from a urine matrix by gas chromatography.

Other Notes

用于脂肪酸的酯化反应的试剂;综述


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pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

82.4 °F - closed cup

flash_point_c

28 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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N,N-Dimethylformamide Diethyl Acetal.
Pindur U.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
J.P. Thenot et al.
Analytical Letters, 217-217 (1972)
DeWolfe RH.
Carboxylic Ortho Acid Derivatives: Preparation and Synthetic Applications (Academic press), 14, 424-424 (2012)



全球贸易项目编号

货号GTIN
CBR02030-1G04061825140148
40252-100ML-F04061837014987
40252-25ML-F04061831985917