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Merck
CN

43530

LC-MS 利血平标准溶液

analytical standard, for LC-MS

别名:

利血平, (3β, 16β, 17α, 18β, 20α)-11,17-二甲氧基-18-[(3,4,5-三甲氧基苯甲酰基)氧基]育亨烷-16-羧酸甲酯

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关于此项目

经验公式（希尔记法）:
C33H40N2O9
化学文摘社编号:
50-55-5
分子量:
608.68
UNSPSC Code:
41121800
NACRES:
NB.21
PubChem Substance ID:
329756346
MDL number:
MFCD00005091
Beilstein/REAXYS Number:
102014

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产品名称

LC-MS 利血平标准溶液, analytical standard, for LC-MS

InChI

1S/C33H40N2O9/c1-38-19-7-8-20-21-9-10-35-16-18-13-27(44-32(36)17-11-25(39-2)30(41-4)26(12-17)40-3)31(42-5)28(33(37)43-6)22(18)15-24(35)29(21)34-23(20)14-19/h7-8,11-12,14,18,22,24,27-28,31,34H,9-10,13,15-16H2,1-6H3/t18-,22+,24-,27-,28+,31+/m1/s1

SMILES string

CO[C@H]1[C@@H](C[C@@H]2CN3CCc4c([nH]c5cc(OC)ccc45)[C@H]3C[C@@H]2[C@@H]1C(=O)OC)OC(=O)c6cc(OC)c(OC)c(OC)c6

InChI key

QEVHRUUCFGRFIF-MDEJGZGSSA-N

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

concentration

5 mg/L in water: isopropyl alcohol (1:1)

technique(s)

LC/MS: suitable

mp

~265 °C (dec.)

suitability

corresponds for mass spectrometry

storage temp.

2-8°C

Quality Level

100

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相关类别

Biochem/physiol Actions

抑制儿茶酚胺和血清素的囊泡摄取。

Application

It was used as mass recalibration standard in coupling capillary electrophoresis with electrospray ionization time-of-flight mass spectrometry (CE-TOFMS) to overcome the problem of decreasing the sensitivity during the detection of metabolome differential display.

General description

Reserpine is a 36 carbon indole alkaloid mostly used as a tranquilizing agent in medicine. It is mostly used as drug for hypertension.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

71.6 °F - closed cup

flash_point_c

22.0 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCM7436
BCCL1270
BCCJ8585
BCCG8168
BCCF8749

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Stimulation of reserpine biosynthesis in the callus of Rauvolfia tetraphylla L. by precursor feeding.
Anitha, S and BD Ranjitha Kumari
African Journal of Biotechnology, 5.8, 659-659 (2006)
Tomoyoshi Soga et al.
The Journal of biological chemistry, 281(24), 16768-16776 (2006-04-13)
Metabolomics is an emerging tool that can be used to gain insights into cellular and physiological responses. Here we present a metabolome differential display method based on capillary electrophoresis time-of-flight mass spectrometry to profile liver metabolites following acetaminophen-induced hepatotoxicity. We
Naomi S Rajapaksa et al.
Organic letters, 15(3), 706-709 (2013-01-22)
A catalytic, enantioselective synthesis of (+)-reserpine is reported. The route features a highly diastereoselective, chiral catalyst-controlled formal aza-Diels-Alder reaction between a 6-methoxytryptamine-derived dihydro-β-carboline and an enantioenriched α-substituted enone to form a key tetracyclic intermediate. This approach addresses the challenge of
Alexander C Sutton et al.
Journal of neurophysiology, 109(2), 363-374 (2012-10-19)
Deep brain stimulation (DBS) employing high-frequency stimulation (HFS) is commonly used in the globus pallidus interna (GPi) and the subthalamic nucleus (STN) for treating motor symptoms of patients with Parkinson's disease (PD). Although DBS improves motor function in most PD
Kari A Johnson et al.
Neuropharmacology, 66, 187-195 (2012-05-02)
Metabotropic glutamate receptors (mGlus) are 7 Transmembrane Spanning Receptors (7TMs) that are differentially expressed throughout the brain and modulate synaptic transmission at both excitatory and inhibitory synapses. Recently, mGlus have been implicated as therapeutic targets for many disorders of the
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