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44028

环己烯

Name: 环己烯
Brand: SIAL

analytical standard, ≥99.5% (GC)

别名:

四氢化苯

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关于此项目

经验公式（希尔记法）:

C₆H₁₀

化学文摘社编号:

110-83-8

分子量:

82.14

NACRES:

NA.24

PubChem Substance ID:

329756445

EC Number:

203-807-8

Beilstein/REAXYS Number:

906737

MDL number:

MFCD00001539

UNSPSC Code:

12141716

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grade

analytical standard

Quality Level

100

vapor density

2.8 (vs air)

vapor pressure

160 mmHg ( 20 °C)

assay

≥99.5% (GC)

autoignition temp.

590 °F

shelf life

limited shelf life, expiry date on the label

contains

~0.01% 2,6-di-tert-butyl-4-methylphenol as stabilizer

expl. lim.

5 %

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

refractive index

n20/D 1.446

bp

83 °C (lit.)

mp

−104 °C (lit.)

density

0.811 g/mL at 25 °C (lit.)

application(s)

environmental
petroleum

format

neat

SMILES string

C1CCC=CC1

InChI

1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2

InChI key

HGCIXCUEYOPUTN-UHFFFAOYSA-N

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pictograms

GHS02,GHS08,GHS07,GHS09

signalword

Danger

hcodes

H225,H302,H304,H411

pcodes

P210 - P233 - P240 - P273 - P301 + P310 - P331

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.4 °F

flash_point_c

-17 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

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Asymmetric synthesis of cyclohexene nucleoside analogues.

Sylvain Dalençon et al.

The Journal of organic chemistry, 76(19), 8059-8063 (2011-08-26)

The asymmetric synthesis of novel cyclohexene nucleoside analogues 12 and 15 is described. An enantiospecific Diels-Alder reaction between (E,E)-diene 2 and (+)-5-(d-mentyloxy)-2(5H)-furanone 3 provided the cycloadduct isomer 4. Three additional steps yielded amine 8 allowing the constructions of the thymine

Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) complex: evidence for an iron(IV)-oxo-hydroxo oxidant from O2.

Sayantan Paria et al.

Angewandte Chemie (International ed. in English), 50(47), 11129-11132 (2011-10-01)

Trimetallic magnesium complexes bearing amine-bis(benzotriazole phenolate) derivatives as bifunctional catalysts for ring-opening polymerization and CO2/epoxide coupling.

Chen-Yu Li et al.

Chemical communications (Cambridge, England), 48(77), 9628-9630 (2012-08-23)

New trimetallic magnesium complexes were synthesized for bifunctional catalysis. Complex catalysed ε-caprolactone polymerizations in not only a 'living' manner but also in an 'immortal' fashion. Additionally, tri-Mg was active for the coupling of CO(2) with cyclohexene oxide (CHO) on addition

Conformational analysis of δ-lactones by DFT calculations: the parent compound and its monomethyl and selected dimethyl derivatives.

Fabian Weber et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 19(4), 1288-1302 (2013-01-09)

The static and dynamic stereochemistry of unsubstituted δ-valerolactone, all monomethylated δ-lactones, and all nongeminally dimethylated δ-lactones was explored with the B3LYP functional and def2-TZVPP basis set. A search strategy was employed which allowed the entire conformational space of any (poly-)substituted

Essential structure of opioid κ receptor agonist nalfurafine for binding to the κ receptor 2: synthesis of decahydro(iminoethano)phenanthrene derivatives and their pharmacologies.

Hiroshi Nagase et al.

Bioorganic & medicinal chemistry letters, 22(15), 5071-5074 (2012-06-30)

To clarify the essential structures of an opioid κ receptor selective agonist, nalfurafine, for binding to the κ receptor, we designed and synthesized some nalfurafine derivatives and the decahydro(iminoethano)phenanthrene derivatives with a cyclohexene moiety as a surrogate for the phenol

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全球贸易项目编号

货号	GTIN
422959-250ML	04061832103280
44028-5ML-F	04061832253220
44028-10ML-F	04061832253213

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