44028
环己烯
analytical standard, ≥99.5% (GC)
别名:
四氢化苯
等级
analytical standard
质量水平
蒸汽密度
2.8 (vs air)
蒸汽压
160 mmHg ( 20 °C)
方案
≥99.5% (GC)
自燃温度
590 °F
保质期
limited shelf life, expiry date on the label
包含
~0.01% 2,6-di-tert-butyl-4-methylphenol as stabilizer
expl. lim.
5 %
技术
HPLC: suitable
gas chromatography (GC): suitable
折射率
n20/D 1.446 (lit.)
n20/D 1.446
沸点
83 °C (lit.)
mp
−104 °C (lit.)
密度
0.811 g/mL at 25 °C (lit.)
应用
environmental
petroleum
包装形式
neat
SMILES字符串
C1CCC=CC1
InChI
1S/C6H10/c1-2-4-6-5-3-1/h1-2H,3-6H2
InChI key
HGCIXCUEYOPUTN-UHFFFAOYSA-N
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应用
关于适当仪器技术的更多信息，请参考产品的检验报告。联系技术服务部提供进一步支持。
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
1.4 °F
闪点(°C)
-17 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Sylvain Dalençon et al.
The Journal of organic chemistry, 76(19), 8059-8063 (2011-08-26)
The asymmetric synthesis of novel cyclohexene nucleoside analogues 12 and 15 is described. An enantiospecific Diels-Alder reaction between (E,E)-diene 2 and (+)-5-(d-mentyloxy)-2(5H)-furanone 3 provided the cycloadduct isomer 4. Three additional steps yielded amine 8 allowing the constructions of the thymine
Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) complex: evidence for an iron(IV)-oxo-hydroxo oxidant from O2.
Sayantan Paria et al.
Angewandte Chemie (International ed. in English), 50(47), 11129-11132 (2011-10-01)
Jan Lennard Wolf et al.
Physical chemistry chemical physics : PCCP, 13(23), 10952-10964 (2011-03-29)
The gas-phase ozonolysis of cyclic-alkenes (1-methyl-cyclohexene, methylene-cyclohexane, α-pinene, β-pinene) is studied with respect to the pressure dependent formation of secondary organic aerosol (SOA). We find that SOA formation is substantially suppressed at lower pressures for all alkenes under study. The
Amelia W Ray et al.
The journal of physical chemistry. A, 116(25), 6720-6730 (2012-05-29)
Earlier synchrotron photoionization mass spectrometry experiments suggested a prominent ring-opening channel in the OH-initiated oxidation of cyclohexene, based on comparison of product photoionization spectra with calculated spectra of possible isomers. The present work re-examines the OH + cyclohexene reaction, measuring
Fabian Weber et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(4), 1288-1302 (2013-01-09)
The static and dynamic stereochemistry of unsubstituted δ-valerolactone, all monomethylated δ-lactones, and all nongeminally dimethylated δ-lactones was explored with the B3LYP functional and def2-TZVPP basis set. A search strategy was employed which allowed the entire conformational space of any (poly-)substituted
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