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Merck
CN

45331

甲基吡啶磷(甲基吡恶磷)

PESTANAL®, analytical standard

别名:

S-((6-Chloro-2-oxooxazolo[4,5-b]pyridin-3(2H)-yl)methyl) O,O-dimethyl phosphorothioate

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关于此项目

经验公式（希尔记法）:
C9H10ClN2O5PS
化学文摘社编号:
35575-96-3
分子量:
324.68
NACRES:
NA.24
PubChem Substance ID:
329756653
UNSPSC Code:
41116107
EC Number:
252-626-0
MDL number:
MFCD00867611

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InChI key

VNKBTWQZTQIWDV-UHFFFAOYSA-N

InChI

1S/C9H10ClN2O5PS/c1-15-18(14,16-2)19-5-12-8-7(17-9(12)13)3-6(10)4-11-8/h3-4H,5H2,1-2H3

SMILES string

COP(=O)(OC)SCN1C(=O)Oc2cc(Cl)cnc12

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

Quality Level

100

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相关类别

General description

Azamethiphos is classified under the heterocyclic organothiophosphate group of compounds.

Application

Azamethiphos may be used as an analytical reference standard for the determination of azamethiphos in:
  • Salmon feed samples by ultra-high performance liquid chromatography combined with traveling-wave ion mobility/quadrupole time-of-flight mass spectrometry (UHPLC-TWIMS-QTOFMS).
  • Surface water samples by solid-phase extraction (SPE) and LC coupled to quadrupole-Orbitrap high resolution tandem mass spectrometry (Q-Orbitrap-MS).
  • Fish fillet samples by QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction and LC-QTOFMS.
  • Human serum samples by QuEChERS combined with LC coupled to tandem mass spectrometry (MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1 - STOT SE 1

target_organs

Nervous system

存储类别

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

农药列管产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN5890
BCCF3468
BCBV5727
BCBS0605V

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Anders Fallang et al.
Pest management science, 60(12), 1163-1170 (2004-12-04)
Acetylcholinesterase (AChE) is the target of a major pesticide family, the organophosphates, which were extensively used as control agents of sea lice on farmed salmonids in the early 1990s. From the mid-1990s the organophosphates dichlorvos and azamethiphos were seriously compromised
L E Burridge et al.
Ecotoxicology and environmental safety, 43(2), 165-169 (1999-06-22)
The pesticide formulation Salmosan (47.5% w/w azamethiphos) is currently registered for use, in Canada, to treat salmonids for infestations of the copepod parasites, Lepeophtheirus salmonis and Caligus elongatus (sea lice). Determination was made of the acute lethality of this product
M N Canty et al.
Marine pollution bulletin, 54(4), 396-402 (2007-02-03)
Concern has been raised that the increased use of pesticides in intensive aquaculture practices may cause adverse sublethal effects to non-target aquatic species. Azamethiphos is an organophosphate (OP) pesticide used to combat sea lice infestations in farmed salmonids. Here, the
W Ernst et al.
Marine pollution bulletin, 42(6), 433-444 (2001-07-27)
Pesticides are used extensively in the finfish aquaculture industry to control sea lice infestations on farmed salmon. The most prevalent method of use is to enclose a net pen with an impervious tarpaulin and mix a pesticide solution within that
Targeted approach for qualitative screening of pesticides in salmon feed by liquid chromatography coupled to traveling-wave ion mobility/quadrupole time-of-flight mass spectrometry.
Regueiro J, et al.
Food Control, 78(4), 116-125 (2017)
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实验方案

Testing Food for Fipronil Contamination

Test your food for fipronil contamination using our analytical standards, certified reference materials, solvents, and columns for analysis.

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