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Merck
CN

45521

草甘膦

PESTANAL®, analytical standard

别名:

N-(磷酰基甲基)甘氨酸, 草甘膦

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关于此项目

线性分子式:
(HO)2P(O)CH2NHCH2CO2H
化学文摘社编号:
1071-83-6
分子量:
169.07
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329756808
EC Number:
213-997-4
Beilstein/REAXYS Number:
2045054
MDL number:
MFCD00055350

主要文件

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InChI key

XDDAORKBJWWYJS-UHFFFAOYSA-N

InChI

1S/C3H8NO5P/c5-3(6)1-4-2-10(7,8)9/h4H,1-2H2,(H,5,6)(H2,7,8,9)

SMILES string

OC(=O)CNCP(O)(O)=O

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

mp

230 °C (dec.) (lit.)

application(s)

agriculture
environmental

format

neat

Quality Level

100

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相关类别

General description

草甘膦是一种非选择性、广谱、多年生除草剂，用于杂草芽后期和植被防除。

Application

有关合适的仪器技术的更多信息，请参阅产品的分析证书。想要获得更多支持，请联系技术服务部。
草甘膦可用作不同色谱技术定量检测水果、蔬菜和环境样品中分析物的分析参考标准品。

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Aquatic Chronic 2 - Eye Dam. 1

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

农药列管产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCJ2151
BCCC7102
BCBZ6585
BCBW9283
BCBV0664

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Determination of glyphosate by ion chromatography
Zhu Y, et al.
Talanta, 850(1-2), 297-301 (1999)
Glyphosate: A Unique Global Herbicide (1997)
Re-evaluation of glyphosate determination in water by liquid chromatography coupled to electrospray tandem mass spectrometry
Ibanez M, et al.
Journal of Chromatography A, 1134(1-2), 51-55 (2006)
Stephen O Duke
Journal of agricultural and food chemistry, 59(11), 5835-5841 (2010-10-06)
High levels of aminomethylphosphonic acid (AMPA), the main glyphosate metabolite, have been found in glyphosate-treated, glyphosate-resistant (GR) soybean, apparently due to plant glyphosate oxidoreductase (GOX)-like activity. AMPA is mildly phytotoxic, and under some conditions the AMPA accumulating in GR soybean
Martin M Vila-Aiub et al.
Pest management science, 69(2), 228-232 (2012-12-21)
Glyphosate resistance in populations of the C(4) perennial Sorghum halepense (Johnsongrass) and C(3) annual Lolium rigidum (rigid ryegrass) has evolved and been documented in many cropping areas around the globe. In S. halepense and in the majority of reported cases
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商品

LC/MS/MS Method for Determination of Glyphosate, AMPA, and Glufosinate in Cereals

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

Simplified LC-MS/MS for Herbicides in Cereals

Glyphosate analysis: LC-MS/MS method with Supel™ Carbon LC U/HPLC column for stability and retention.

LC/MS/MS法测定谷物中的草甘膦、AMPA和草铵膦

使用 HPLC 和 SPE 的离子交换聚合物基颗粒测定燕麦片和婴儿谷物中的草甘膦及相关化合物。获得低水平的检测结果。

实验方案

EPA Method 547: HPLC Analysis of Glyphosate and Glyphosate Degradation Product (Aminomethyl)phosphonic Acid (AMPA)

EPA Method 547 outlines the analysis of glyphosate in drinking water by direct aqueous injection HPLC, post column derivatization, and fluorescence detection

LC/MS Analysis of Glyphosate and Metabolites on apHera™ NH2, 2 mm I.D. Column

LC/MS Analysis of Glyphosate and Metabolites on apHera™ NH2, 2 mm I.D. Column

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