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Merck
CN

517127

碳酸二甲酯

greener alternative

anhydrous, ≥99%

别名:

DMC, 碳酸二甲酯

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关于此项目

线性分子式:
(CH3O)2CO
化学文摘社编号:
分子量:
90.08
UNSPSC Code:
12352108
NACRES:
NA.21
PubChem Substance ID:
EC Number:
210-478-4
Beilstein/REAXYS Number:
635821
MDL number:
Grade:
anhydrous
Assay:
≥99%
Bp:
90 °C (lit.)
Vapor pressure:
18 mmHg ( 21.1 °C)
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产品名称

碳酸二甲酯, anhydrous, ≥99%

InChI key

IEJIGPNLZYLLBP-UHFFFAOYSA-N

InChI

1S/C3H6O3/c1-5-3(4)6-2/h1-2H3

SMILES string

O=C(OC)OC

grade

anhydrous

vapor density

3.1 (vs air)

vapor pressure

18 mmHg ( 21.1 °C)

assay

≥99%

form

liquid

expl. lim.

4.22-12.87 % (lit.)

greener alternative product characteristics

Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Design for Degradation
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

<0.002% water
<0.005% water (100mL pkg)

color

APHA: <50

refractive index

n20/D 1.368 (lit.)

bp

90 °C (lit.)

mp

2-4 °C (lit.)

density

1.069 g/mL at 25 °C (lit.)

greener alternative category

Quality Level

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Application

碳酸二甲酯已被用于溶解聚(乳酸 --羟基乙酸)(PLGA)以形成PLGA涂覆的生物活性玻璃-陶瓷支架。

Features and Benefits

更环保溶剂

General description

碳酸二甲酯(DMC)是一种多功能、无毒、可生物降解的试剂,具有可调节的化学反应性。它可作为硫酸二甲酯或卤代甲烷和光气的绿色替代物,可用于甲基化和羧化反应。DMC可以通过二氧化碳和甲醇之间的碱催化反应来制备。

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。此产品更加绿色环保,是传统溶剂和化学制剂的替代品。点击此处以获取更多信息。

pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

60.8 °F - closed cup

flash_point_c

16 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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分析证书(COA)

Lot/Batch Number

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Preparation and characterisation of plga-coated porous bioactive glass-ceramic scaffolds for subchondral bone tissue engineering.
O'Shea TM and Miao X.
Proceeding of the 9th International Symposium on Ceramic Materials and Components for Energy and Environmental Applications (2009)
Hao Sun et al.
Nature communications, 10(1), 3302-3302 (2019-07-26)
Rechargeable sodium metal batteries with high energy density could be important to a wide range of energy applications in modern society. The pursuit of higher energy density should ideally come with high safety, a goal difficult for electrolytes based on
Direct synthesis of dimethyl carbonate from carbon dioxide and methanol catalyzed by base.
Fang S and Fujimoto K.
Applied Catalysis A: General, 142(1), L1-L3 (1996)
Transesterification of cyclic carbonates to dimethyl carbonate using solid oxide catalyst at ambient conditions: environmentally benign synthesis.
Meenakshisundaram Sankar et al.
ChemSusChem, 3(5), 575-578 (2010-04-02)
Yongjiang Gan et al.
Carbohydrate research, 346(3), 389-392 (2011-02-08)
A novel green synthesis process about methyl-β-cyclodextrin has been investigated through the reaction between β-cyclodextrin and dimethyl carbonate by anhydrous potassium carbonate as catalyst in DMF. The influence of experimental factors including the molar ratio of dimethyl carbonate to β-cyclodextrin

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