59640
硝酸异丙酯
purum, ≥98.0% (GC)
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线性分子式:
(CH3)2CHONO2
化学文摘社编号:
分子量:
105.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-983-6
Beilstein/REAXYS Number:
1701405
MDL number:
Assay:
≥98.0% (GC)
InChI
1S/C3H7NO3/c1-3(2)7-4(5)6/h3H,1-2H3
InChI key
GAPFWGOSHOCNBM-UHFFFAOYSA-N
SMILES string
CC(C)O[N+]([O-])=O
grade
purum
assay
≥98.0% (GC)
bp
101-102 °C (lit.)
density
1.040 g/mL at 20 °C (lit.)
General description
硝酸异丙酯可通过硝酸和尿素硝化异丙醇获得。
Application
硝酸异丙酯是一种具有较大爆轰长度的单组分推进剂。这可以提高诊断分辨率，因此它可以作为硝基甲烷的替代品，用于研究均质液体炸药。它还可用于合成1,2-二甲氧基-4-（硝基甲基）苯，这是一种硝基烷烃衍生物，可在连续流反应器中通过Nef氧化法将其转化为相应的羧酸。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
51.8 °F - closed cup
flash_point_c
11 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Spyra W and Winkelmann K
The Conversion of Liquid Rocket Fuels, 162 (2006)
Shock initiation and detonability of isopropyl nitrate
Zhang F and Murray.BS
12th International Detonation Symposium. (2002)
"KMnO4-mediated oxidation as a continuous flow process"
Sedelmeier J, et al.
Organic Letters, 12(16), 3618- 3621 (2002)
Poppers-associated retinal toxicity.
Catherine Vignal-Clermont et al.
The New England journal of medicine, 363(16), 1583-1585 (2010-10-15)
I Ahonen et al.
Toxicology letters, 47(2), 205-211 (1989-05-01)
Four healthy men were exposed to an isopropyl nitrate (IPN) concentration of 45.8 mg/m3 for 60 min. The IPN in the expired air, blood and urine of volunteers was analysed by gas chromatography. The longest elimination half-time of IPN by
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