62136
(+)-反式-柠檬烯 1,2-环氧化物
analytical standard
别名:
(+)-反式-对-薄荷-1,8-二烯 1,2-环氧化物, (1S,2R,4R)-4-异丙烯基-1-甲基-1-环己烯 1,2-环氧化物, (1S,4R)-1,2-环氧-对-薄荷-8-烯
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关于此项目
经验公式（希尔记法）:
C10H16O
化学文摘社编号:
分子量:
152.23
Beilstein:
80940
MDL编号:
UNSPSC代码:
85151701
PubChem化学物质编号:
NACRES:
NA.24
等级
analytical standard
方案
≥95.0% (sum of enantiomers, GC)
旋光性
[α]20/D +90±2°, neat
保质期
limited shelf life, expiry date on the label
技术
HPLC: suitable
gas chromatography (GC): suitable
折射率
n20/D 1.466
密度
0.930 g/mL at 20 °C (lit.)
应用
food and beverages
包装形式
neat
储存温度
2-8°C
SMILES字符串
CC([C@@H]1CC[C@@]2(C)[C@@](O2)([H])C1)=C
InChI
1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9-,10+/m1/s1
InChI key
CCEFMUBVSUDRLG-BBBLOLIVSA-N
应用
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
149.0 °F - closed cup
闪点(°C)
65 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
L D Lehman-McKeeman et al.
Toxicology and applied pharmacology, 116(2), 170-176 (1992-10-01)
The rate-limiting step in chemically induced, male rat-specific hyaline droplet nephropathy is the reversible binding of a xenobiotic to alpha 2u-globulin. In this study, equilibrium saturation binding experiments were conducted to evaluate the in vitro binding of d-limonene-1,2-oxide (dLO) and
J S Prescott-Mathews et al.
Toxicology and applied pharmacology, 157(1), 60-67 (1999-05-18)
Methyl tert-butyl ether (MTBE), a fuel additive blended into unleaded gasoline, decreases emissions of selected air pollutants. Exposure to MTBE causes a low incidence of renal tumors in male, but not female, F-344 rats. A number of chemicals that cause
J W Regan et al.
Xenobiotica; the fate of foreign compounds in biological systems, 10(12), 859-861 (1980-12-01)
1. The metabolism of limonene-1,2-epoxide was studied following intraperitoneal injection in rats and in rat liver homogenates. 2. Limonene-1,2-glycol was the only neutral metabolite detected. Major limonene metabolites, p-mentha-2,8-dien-1-alpha and -beta-ol and p-mentha-1,8-dien-6-alpha and -beta-ol were not observed. 3. Limonene-1,2-epoxide
Maliha Uroos et al.
The Journal of organic chemistry, 75(24), 8465-8470 (2010-11-23)
A total synthesis of (+)-cymbodiacetal (1) has been completed from (R)-(+)-limonene oxide using a hetero-Diels-Alder cycloaddition as a key step. The key Diels-Alder cycloaddition proceeds with endo-selectivity (2:1, endo/exo) in quantitative yield, and the two diastereomeric spirochroman products are isolable
M J van der Werf et al.
Journal of bacteriology, 180(19), 5052-5057 (1998-09-28)
An epoxide hydrolase from Rhodococcus erythropolis DCL14 catalyzes the hydrolysis of limonene-1,2-epoxide to limonene-1,2-diol. The enzyme is induced when R. erythropolis is grown on monoterpenes, reflecting its role in the limonene degradation pathway of this microorganism. Limonene-1,2-epoxide hydrolase was purified
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