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Merck
CN

64120

甲基丙烯酰氯

purum, dist., ≥97.0% (GC), contains ~0.02% 2,6-di-tert-butyl-4-methylphenol as stabilizer

别名:

甲基丙烯酰氯, 甲基丙烯酸氯

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线性分子式:
CH2=C(CH3)COCl
化学文摘社编号:
分子量:
104.53
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
213-058-9
Beilstein/REAXYS Number:
878175
MDL number:
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InChI key

VHRYZQNGTZXDNX-UHFFFAOYSA-N

InChI

1S/C4H5ClO/c1-3(2)4(5)6/h1H2,2H3

SMILES string

CC(=C)C(Cl)=O

grade

purum

assay

≥97.0% (GC)

quality

dist.

contains

~0.02% 2,6-di-tert-butyl-4-methylphenol as stabilizer

impurities

≤1000 mg/kg total sulfur (as SO4)

refractive index

n20/D 1.442 (lit.), n20/D 1.444

bp

95-96 °C (lit.)

density

1.08 g/mL at 20 °C, 1.07 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

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General description

甲基丙烯酰氯是甲基丙烯酸的酰氯,在聚合物领域中用作单体或合成各种聚合物的反应中间体。它被用于合成各种聚合物,比如聚甲基丙烯酰氯、聚甲基丙烯酸酯和聚甲基丙烯酰胺,广泛应用于包括齿科材料,粘合剂,隐形眼镜,水凝胶,涂料的生产和各种生物医疗器械的开发。

Application

甲基丙烯酰氯可用作:
  • 通过可逆加成-断裂链转移 (RAFT) 聚合合成两亲性荧光共聚物的单体。由此产生的共聚物具有智能pH敏感和荧光性能,这使它们适用于细胞成像。
  • 在乳液聚合过程中用于制备荧光探针的单体,该探针用于检测甲硝唑。
  • 微晶纤维素(MCC)的表面活性剂,用于制备低密度聚乙烯(LDPE)基复合材料时改善LDPE的相容性。
  • 羧甲基纤维素丙烯酸酯合成中的关键成分,可用于 pH 敏感水凝胶的开发。
  • 合成甲基丙烯酸酯基水凝胶材料的单体,它可广泛应用与生产软性隐形眼镜。
甲基丙烯酰氯也可用于:
  • 制备带有甲基丙烯酰基官能团的苯并噁嗪单体。
  • 作为制备金属螯合单体 N-甲基丙烯酰-(L)-组氨酸甲基酯(MAH)的前体。

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

55.0 °F - closed cup

flash_point_c

12.8 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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