64258
甲基膦酸二甲酯
purum, ≥97.0% (GC)
别名:
Dimethoxymethyl phosphine oxide, Fyrol DMMP, Methanephosphonic acid dimethyl ester, NSC 62240, Reoflam DMMP
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关于此项目
线性分子式:
CH3P(O)(OCH3)2
化学文摘社编号:
分子量:
124.08
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-052-3
Beilstein/REAXYS Number:
878263
MDL number:
Assay:
≥97.0% (GC)
InChI key
VONWDASPFIQPDY-UHFFFAOYSA-N
InChI
1S/C3H9O3P/c1-5-7(3,4)6-2/h1-3H3
SMILES string
COP(C)(=O)OC
vapor pressure
<0.1 mmHg ( 20 °C)
grade
purum
assay
≥97.0% (GC)
reaction suitability
reaction type: C-C Bond Formation
Quality Level
bp
181 °C (lit.)
density
1.145 g/mL at 25 °C (lit.)
functional group
phosphonate
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Application
Dimethyl methylphosphonate (DMPP) is generally used as a model compound for catalytic degradation studies due to its structural similarity to the organophosphorus compounds used in chemical warfare agents, pesticides and herbicides.
Used to test SXFA-coated SAW chemical sensors for organophosphorous compound detection
Used as a chemical agent simulant for testing of protective performance of PSS membranes and functionalized sorbent membranes
Reactant for photocatalytic oxidation
Additive for synthesis of:
Used as a chemical agent simulant for testing of protective performance of PSS membranes and functionalized sorbent membranes
Reactant for photocatalytic oxidation
Additive for synthesis of:
- Flame retardant high phosphorous containing unsaturated polyester resin
- UV-cured epoxy acrylate / microencapsulated phase change material
Other Notes
简便的 Wittig-Horner 试剂
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Muta. 1B - Repr. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
156.2 °F - closed cup
flash_point_c
69 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Enhanced photocatalytic degradation of dimethyl methylphosphonate in the presence of low-frequency ultrasound
Chen Y-C, et al.
Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology, 2(6), 694-698 (2003)
Adsorption and decomposition of dimethyl methylphosphonate on TiO2
Rusu CN and Yates JT
The Journal of Physical Chemistry B, 104(51), 12292-12298 (2000)
Study of the catalytic destruction of dimethyl methylphosphonate (DMMP): oxidation over molybdenum (110)
Smentkowski VS, et al.
The Journal of Physical Chemistry, 92(22), 6351-6357 (1988)
P.A. Aristoff
The Journal of Organic Chemistry, 50, 1765-1765 (1985)
Cristina Tudisco et al.
Langmuir : the ACS journal of surfaces and colloids, 28(3), 1782-1789 (2011-12-22)
This paper reports on the preparation of a porous silicon-based material covalently functionalized with cavitand receptors suited for the detection of organophosphorus vapors. Two different isomeric cavitands, both containing one acid group at the upper rim, specifically designed for covalent
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