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Merck
CN

648531

N,N-二甲基甲酰胺

suitable for HPLC, ≥99.9%

别名:

DMF, NSC 5356

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线性分子式:
HCON(CH3)2
化学文摘社编号:
分子量:
73.09
EC Number:
200-679-5
UNSPSC Code:
12190000
PubChem Substance ID:
Beilstein/REAXYS Number:
605365
MDL number:
Assay:
≥99.9%
Grade:
HPLC grade
Technique(s):
HPLC: suitable
Bp:
153 °C (lit.)
Vapor pressure:
2.7 mmHg ( 20 °C)
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Quality Level

grade

HPLC grade

vapor pressure

2.7 mmHg ( 20 °C)

assay

≥99.9%

form

liquid

autoignition temp.

833 °F

expl. lim.

15.2 %

technique(s)

HPLC: suitable

impurities

≤0.030% water

evapn. residue

≤0.0005%

bp

153 °C (lit.)

mp

−61 °C (lit.)

density

0.944 g/mL (lit.)

absorption

0.010 at 340 nm, 0.010 at 400 nm, 0.05 at 310 nm, 0.10 at 295 nm, 0.30 at 275 nm, 1.00 at 270 nm

application(s)

food and beverages

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General description

N,N-Dimethylformamide (DMF) is the commonly employed solvent for chemical reactions. DMF is a useful solvent employed for the isolation of chlorophyll from plant tissues. It is widely employed reagent in organic synthesis. It plays multiple roles in various reactions such as solvent, dehydrating agent, reducing agent as well as catalyst. It is a multipurpose building block for the synthesis of compounds containing O, -CO, -NMe2, -CONMe2, -Me, -CHO as functional groups. Dielectric relaxation experiments on DMF have been conducted between 238.15K and 338.15K. The thermophysical properties of the molecular interactions between DMF and the ionic liquids, ammonium salts and imidazolium salts have been studied. The characteristics of solute-solvent interactions between ammonium nitrate and DMF have been investigated.

Application

多种疏水性有机化合物的溶剂。

Packaging

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
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Other Notes

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

135.5 °F - closed cup

flash_point_c

57.5 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis and electrochemical characterization of aPEO-based polymer electrolytes.
Rodrigues LC, et al.
Journal of Solid State Electrochemistry, 16(4), 1623-1629 (2012)
The dynamics of liquid formamide, N-methylformamide, N,N-dimethylformamide, and N,N-dimethylacetamide. A dielectric relaxation study.
Barthel J, et al.
Journal of Molecular Liquids, 98, 51-69 (2002)
Measurements and molecular interactions for N,N-dimethylformamide with ionic liquid mixed solvents.
Attri P, et al.
The Journal of Physical Chemistry B, 114(18), 6126-6133 (2010)
Volumetric properties of ammonium nitrate in N,N-dimethylformamide.
Vranes M, et al.
The Journal of Chemical Thermodynamics, 54, 245-249 (2012)
W P Inskeep et al.
Plant physiology, 77(2), 483-485 (1985-02-01)
We found inconsistencies in the commonly used data for chlorophyll analysis in 80% acetone. Recently developed extinction coefficients for chlorophyll b in N,N-dimethylformamide (DMF) based on values from 80% acetone are low as a result of these inconsistencies. We determined

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