69875
六羰基钼
technical
别名:
羰化钼
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线性分子式:
Mo(CO)6
化学文摘社编号:
分子量:
264.00
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
237-713-3
MDL number:
InChI key
KMKBZNSIJQWHJA-UHFFFAOYSA-N
InChI
1S/6CO.Mo/c6*1-2;
SMILES string
[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
vapor density
9.1 (vs air)
grade
technical
Quality Level
reaction suitability
core: molybdenum, reagent type: catalyst
bp
156 °C (lit.)
mp
150 °C (dec.) (lit.)
density
1.96 g/mL at 25 °C (lit.)
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General description
Molybdenum hexacarbonyl is a colorless compound that sublimates and decomposes without melting at 150oC. It has an octahedral structure. Inherent sublimation of molybdenum hexacarbonyl permits it to perform as an active liquefaction catalyst. To form a catalyst it is adsorbed on dehydroxylated alumina forming subcarboyls.
Application
Alumina supported molybdenum hexacarbonyl acts as an active catalyst. It is used to synthesize MoO and MoC nanowires by electron beam induced deposition.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
An investigation of the chemistry of molybdenum hexacarbonyl on thin dehydroxylated alumina films in ultrahigh vacuum
Catalysis Letters, 91(1-2), 83-88 (2003)
Microstructural analysis and Transport Properties of MoO and MoC nanostructures prepared by focused electron beam-induced deposition
Makise K, et al
Scientific Reports, 4 (2014)
Microwave-promoted aminocarbonylations of aryl chlorides using Mo(CO)(6) as a solid carbon monoxide source.
Olof Lagerlund et al.
Journal of combinatorial chemistry, 8(1), 4-6 (2006-01-10)
Patrik Nordeman et al.
The Journal of organic chemistry, 77(24), 11393-11398 (2012-12-05)
A bridged two-vial system aminocarbonylation protocol where Mo(CO)(6) functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in the
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and
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