71210
乙醇钠
≥95% (T), powder, technical
别名:
乙氧钠
产品名称
乙醇钠, technical, ≥95% (T)
蒸汽密度
1.6 (vs air)
质量水平
蒸汽压
<0.1 mmHg ( 20 °C)
等级
technical
方案
≥95% (T)
表单
powder
杂质
~2% Na2CO3 and NaOH
SMILES字符串
[Na+].CC[O-]
InChI
1S/C2H5O.Na/c1-2-3;/h2H2,1H3;/q-1;+1
InChI key
QDRKDTQENPPHOJ-UHFFFAOYSA-N
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一般描述
乙醇钠是一种烷氧基盐，主要作为强碱用于脱质子化、脱水和脱卤等有机反应。
乙醇钠（乙酸钠）是一种醇钠。它是由钠与乙醇反应合成的。在水存在下发生分解，生成乙醇和氢氧化钠。它被广泛用作有机合成研究的强碱。
应用
三羰基氯（甘氨酸）钌 (II) (CORM-3) 的制备可使用乙醇钠。
乙醇钠可用作钯催化的芳基卤化物和烯基硼烷交叉偶联反应的碱，以合成芳基化 ( E )-烯烃。
警示用语：
Danger
危险声明
危险分类
Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1A
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 1
闪点(°F)
86.0 °F - closed cup
闪点(°C)
30 °C - closed cup
法规信息
监管及禁止进口产品
此项目有
Whitaker KS and Whitaker DT
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst.
Miyaura N & Suzuki, A.
Journal of the Chemical Society. Chemical Communications, 19, 866-867 (1979)
James E Clark et al.
Circulation research, 93(2), e2-e8 (2003-07-05)
Carbon monoxide, which is generated in mammals during the degradation of heme by the enzyme heme oxygenase, is an important signaling mediator. Transition metal carbonyls have been recently shown to function as carbon monoxide-releasing molecules (CO-RMs) and to elicit distinct
Eagleson M.
Concise Encyclopedia Chemistry, 997-997 (1994)
N C Luu et al.
Chemical research in toxicology, 13(7), 610-615 (2000-07-18)
Glutathione conjugate formation plays important roles in the detoxification and bioactivation of xenobiotics. A range of nephrotoxic haloalkenes undergo bioactivation that involves glutathione and cysteine S-conjugate formation. The cysteine S-conjugates thus formed may undergo cysteine conjugate beta-lyase-catalyzed biotransformation to form
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