71210
乙醇钠
≥95% (T), powder, technical
别名:
乙氧钠
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关于此项目
线性分子式:
CH3CH2ONa
化学文摘社编号:
分子量:
68.05
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
205-487-5
MDL number:
Beilstein/REAXYS Number:
3593646
Assay:
≥95% (T)
Form:
powder
产品名称
乙醇钠, technical, ≥95% (T)
InChI key
QDRKDTQENPPHOJ-UHFFFAOYSA-N
InChI
1S/C2H5O.Na/c1-2-3;/h2H2,1H3;/q-1;+1
SMILES string
[Na+].CC[O-]
vapor density
1.6 (vs air)
vapor pressure
<0.1 mmHg ( 20 °C)
grade
technical
assay
≥95% (T)
form
powder
impurities
~2% Na2CO3 and NaOH
Quality Level
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General description
乙醇钠是一种烷氧基盐，主要作为强碱用于脱质子化、脱水和脱卤等有机反应。
乙醇钠（乙酸钠）是一种醇钠。它是由钠与乙醇反应合成的。在水存在下发生分解，生成乙醇和氢氧化钠。它被广泛用作有机合成研究的强碱。
Application
三羰基氯（甘氨酸）钌 (II) (CORM-3) 的制备可使用乙醇钠。
乙醇钠可用作钯催化的芳基卤化物和烯基硼烷交叉偶联反应的碱，以合成芳基化 ( E )-烯烃。
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1A
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
86.0 °F - closed cup
flash_point_c
30 °C - closed cup
法规信息
监管及禁止进口产品
此项目有
Whitaker KS and Whitaker DT
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst.
Miyaura N & Suzuki, A.
Journal of the Chemical Society. Chemical Communications, 19, 866-867 (1979)
James E Clark et al.
Circulation research, 93(2), e2-e8 (2003-07-05)
Carbon monoxide, which is generated in mammals during the degradation of heme by the enzyme heme oxygenase, is an important signaling mediator. Transition metal carbonyls have been recently shown to function as carbon monoxide-releasing molecules (CO-RMs) and to elicit distinct
Eagleson M.
Concise Encyclopedia Chemistry, 997-997 (1994)
N C Luu et al.
Chemical research in toxicology, 13(7), 610-615 (2000-07-18)
Glutathione conjugate formation plays important roles in the detoxification and bioactivation of xenobiotics. A range of nephrotoxic haloalkenes undergo bioactivation that involves glutathione and cysteine S-conjugate formation. The cysteine S-conjugates thus formed may undergo cysteine conjugate beta-lyase-catalyzed biotransformation to form
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