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线性分子式:
CH3CH2C(CH3)2OH
化学文摘社编号:
分子量:
88.15
UNSPSC Code:
12352001
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-908-9
Beilstein/REAXYS Number:
1361351
MDL number:
Grade:
anhydrous
Assay:
≥99%
Bp:
102 °C (lit.)
产品名称
2-甲基-2-丁醇, anhydrous, ≥99%
InChI
1S/C5H12O/c1-4-5(2,3)6/h6H,4H2,1-3H3
InChI key
MSXVEPNJUHWQHW-UHFFFAOYSA-N
SMILES string
CCC(C)(C)O
grade
anhydrous
vapor density
3 (vs air)
assay
≥99%
form
liquid
autoignition temp.
819 °F
expl. lim.
9 %
impurities
≤0.003% water (Karl Fischer, all unit sizes greater than 100 mL)
≤0.005% water (100 mL pkg)
evapn. residue
≤0.0005%
refractive index
n20/D 1.405 (lit.)
pH
6.0 (20 °C, 118 g/L)
bp
102 °C (lit.)
mp
−12 °C (lit.)
density
0.805 g/mL at 25 °C (lit.)
Quality Level
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Application
叔戊醇作为有机溶剂 化学中间体 可用于汽油燃料添加剂 、食品香精 、医药 过氧酯、油墨成分和橡胶生产中的稳定剂。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
68.9 °F - closed cup
flash_point_c
20.5 °C - closed cup
法规信息
危险化学品
此项目有
Chen, C.-X., Wu, Q.
Enz. Microbiol. Technol., 42, 601-601 (2008)
Torsten Weil et al.
Organic letters, 10(8), 1513-1516 (2008-03-28)
We present a mild and efficient method for the completely regioselective alcoholysis of styrene oxides utilizing a cooperative Brønsted acid-type organocatalytic system comprised of mandelic acid (1 mol %) and N,N'-bis-[3,5-bis-(trifluoromethyl)phenyl]-thiourea (1 mol %). Various styrene oxides are readily transformed
Teai, T.; Claude-Lafontaine, A. et al.
J. Essent. Oil Res., 13, 314-314 (2001)
Funk, R.L.; Daily, W.J.; Parvez, D.M.
The Journal of Organic Chemistry, 53, 4143-4143 (1998)
Jiang-Ning Hu et al.
Journal of agricultural and food chemistry, 56(22), 10988-10993 (2008-11-06)
In the lipase (Novozyme 435)-catalyzed synthesis of ginsenoside Rb1 esters, different acyl donors were found to affect not only the degree of conversion but also the regioselectivity. The reaction of acyl donors with short carbon chain was more effective, showing
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