72910
4-硝基苯甲酸
purum, ≥98.0% (HPLC)
别名:
p-Nitrobenzoic acid
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关于此项目
线性分子式:
O2NC6H4CO2H
化学文摘社编号:
分子量:
167.12
Beilstein:
973593
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
等级
purum
质量水平
方案
≥98.0% (HPLC)
表单
crystals
mp
237-240 °C (lit.)
239-242 °C
官能团
carboxylic acid
nitro
SMILES字符串
OC(=O)c1ccc(cc1)[N+]([O-])=O
InChI
1S/C7H5NO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4H,(H,9,10)
InChI key
OTLNPYWUJOZPPA-UHFFFAOYSA-N
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应用
4-Nitrobenzoic acid can be used:
- As a co-catalyst with thioxotetrahydropyrimidinone for the α-alkylation of ketones.
- For the synthesis of mononuclear zinc carboxylate complexes by reacting with zinc sulfate heptahydrate and NaOH.
- As an additive in the room temperature catalytic Wittig reaction.
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Muta. 2 - Repr. 2 - Skin Irrit. 2
储存分类代码
13 - Non Combustible Solids
WGK
WGK 2
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Synthesis and characterization of zinc benzoate complexes through combined solid and solution phase reactions.
Karmakar A and Baruah JB
Polyhedron, 27(17), 3409-3416 (2008)
Enantioselective Organocatalytic ?-Alkylation of Ketones by SN1-Type Reaction of Alcohols.
Trifonidou M and Kokotos CG
European Journal of Organic Chemistry, 2012(8), 1563-1568 (2012)
Breaking the ring through a room temperature catalytic Wittig reaction.
O'Brien CJ, et al.
Chemistry?A European Journal , 19(19), 5854-5858 (2013)
M A Hughes et al.
Journal of bacteriology, 183(4), 1225-1232 (2001-02-07)
Pseudomonas putida strain TW3 is able to metabolize 4-nitrotoluene via 4-nitrobenzoate (4NBen) and 3, 4-dihydroxybenzoic acid (protocatechuate [PCA]) to central metabolites. We have cloned, sequenced, and characterized a 6-kbp fragment of TW3 DNA which contains five genes, two of which
Li Lin et al.
Chemosphere, 78(1), 66-71 (2009-10-23)
This paper describes the microwave (MW) treatment of soil contaminated by chloramphenicol (CAP), using granular activated carbon (GAC) as MW absorbent. It was found that the addition of GAC effectively increased the temperature of soil. Large MW power and GAC
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