73970
N-甲基-N-亚硝基对甲苯磺酰胺
purum, ≥98.0% (HPLC)
别名:
Diazald®, N-Methyl-N-(p-tolylsulfonyl)nitrosamide, N-Nitroso-p-toluenesulfomethylamide, N-亚硝基-N-甲基对甲苯磺酰胺, 对甲苯基磺甲基亚硝酰胺, 重氮甲烷前体
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关于此项目
经验公式（希尔记法）:
C8H10N2O3S
化学文摘社编号:
分子量:
214.24
UNSPSC Code:
12352102
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-252-6
Beilstein/REAXYS Number:
2214345
MDL number:
InChI
1S/C8H10N2O3S/c1-7-3-5-8(6-4-7)14(12,13)10(2)9-11/h3-6H,1-2H3
InChI key
FFKZOUIEAHOBHW-UHFFFAOYSA-N
SMILES string
CN(N=O)S(=O)(=O)c1ccc(C)cc1
grade
purum
assay
≥98.0% (HPLC)
form
crystals
reaction suitability
reaction type: C-C Bond Formation
mp
~58 °C
storage temp.
2-8°C
Quality Level
Preparation Note
Warning: these products are subject to the Explosives Act and must be transported refrigerated - additional costs for transport will apply.
Other Notes
制备重氮甲烷
Legal Information
Diazald is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Self-react. C - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
4.1A - Other explosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
M. Hudlicky
The Journal of Organic Chemistry, 45, 5377-5377 (1980)
Izabela Kania-Korwel et al.
Journal of chromatography. A, 1207(1-2), 146-154 (2008-09-02)
Several polychlorinated biphenyls (PCBs) and their hydroxylated metabolites display axial chirality. Here we describe an enantioselective, gas chromatographic separation of methylated derivatives of hydroxylated (OH-)PCB atropisomers (MeO-PCB) using a chemically bonded beta-cyclodextrin column (Chirasil-Dex). The atropisomers of several MeO-PCBs could
Th.J. De Boer et al.
Organic Syntheses, 4, 250-250 (1963)
Contact dermatitis from Diazald.
H S Young et al.
Contact dermatitis, 50(5), 315-316 (2004-06-24)
M Börzsönyi et al.
Neoplasma, 35(3), 257-262 (1988-01-01)
N-nitroso-N-methyl-p-toluenesulfonamide (NMTS, diazald, CAS 80-11-5) is a widely used compound for laboratory production of diazomethane. The present results showed that the noncarcinogenic NMTS reacts as a transnitrosating agent with amino nitrogen of secondary amines and amide both in vitro (human
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