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Merck
CN

73970

N-甲基-N-亚硝基对甲苯磺酰胺

purum, ≥98.0% (HPLC)

别名:

Diazald®, N-Methyl-N-(p-tolylsulfonyl)nitrosamide, N-Nitroso-p-toluenesulfomethylamide, N-亚硝基-N-甲基对甲苯磺酰胺, 对甲苯基磺甲基亚硝酰胺, 重氮甲烷前体

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关于此项目

经验公式(希尔记法):
C8H10N2O3S
化学文摘社编号:
分子量:
214.24
UNSPSC Code:
12352102
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-252-6
Beilstein/REAXYS Number:
2214345
MDL number:
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grade

purum

Quality Level

assay

≥98.0% (HPLC)

form

crystals

reaction suitability

reaction type: C-C Bond Formation

mp

~58 °C

storage temp.

2-8°C

SMILES string

CN(N=O)S(=O)(=O)c1ccc(C)cc1

InChI

1S/C8H10N2O3S/c1-7-3-5-8(6-4-7)14(12,13)10(2)9-11/h3-6H,1-2H3

InChI key

FFKZOUIEAHOBHW-UHFFFAOYSA-N

Preparation Note

Warning: these products are subject to the Explosives Act and must be transported refrigerated - additional costs for transport will apply.

Other Notes

制备重氮甲烷

Legal Information

Diazald is a registered trademark of Merck KGaA, Darmstadt, Germany


pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Self-react. C - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

4.1A - Other explosive hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

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Lot/Batch Number

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M. Hudlicky
The Journal of Organic Chemistry, 45, 5377-5377 (1980)
Izabela Kania-Korwel et al.
Journal of chromatography. A, 1207(1-2), 146-154 (2008-09-02)
Several polychlorinated biphenyls (PCBs) and their hydroxylated metabolites display axial chirality. Here we describe an enantioselective, gas chromatographic separation of methylated derivatives of hydroxylated (OH-)PCB atropisomers (MeO-PCB) using a chemically bonded beta-cyclodextrin column (Chirasil-Dex). The atropisomers of several MeO-PCBs could
Th.J. De Boer et al.
Organic Syntheses, 4, 250-250 (1963)



全球贸易项目编号

货号GTIN
73970-100G04061833381137