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Merck
CN

76547

稻瘟灵

PESTANAL®, analytical standard

别名:

Diisopropyl 2-(1,3-dithiolan-2-ylidene)malonate

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关于此项目

经验公式(希尔记法):
C12H18O4S2
化学文摘社编号:
分子量:
290.40
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2128528
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InChI

1S/C12H18O4S2/c1-7(2)15-10(13)9(11(14)16-8(3)4)12-17-5-6-18-12/h7-8H,5-6H2,1-4H3

SMILES string

CC(C)OC(=O)\C(C(=O)OC(C)C)=C1/SCCS1

InChI key

UFHLMYOGRXOCSL-UHFFFAOYSA-N

grade

analytical standard

product line

PESTANAL®

assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

Quality Level

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General description

Isoprothiolane is a systemic fungicide, which is used in controlling diseases rice stem rot, rice blast and Fusarium leaf spot on rice. Its mode of action basically involves the inhibition of penetration and elongation of infecting hyphae via inhibiting the formation of infecting peg or cellulose secretion.

Application

Isoprothiolane may be used as a reference standard in the determination of isoprothiolane in food samples using gas chromatography coupled with mass spectrometry (GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

农药列管产品
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分析证书(COA)

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S S Chou et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 15(2), 135-146 (1980-01-01)
The fungicide isoprothiolane (diisopropyl 1,3-dithiolan-2-ylidenemalonate) decomposed slowly in deionized water under ultraviolet light or sunlight irradiation. Rice-paddy water greatly accelerated the photodegradation. This photosensitizing effect was comparable to that of 2% acetone. Soil extracts, rice-plant extracts, and chlorophylls showed little
Metabolic Pathways of Agrochemicals: Insecticides and fungicides (1998)
Y Matsui et al.
Water science and technology : a journal of the International Association on Water Pollution Research, 56(1), 71-80 (2007-08-23)
Verification of a diffuse pollution model involves comparing results actually observed with those predicted by precise model inputs. Acquisition of precise model inputs is, however, problematic. In particular, when the target catchment is large and substantial estimation uncertainty exists, not
S Nagasawa et al.
Nihon juigaku zasshi. The Japanese journal of veterinary science, 51(2), 284-293 (1989-04-01)
Isoprothiolane was administered continuously of various doses to heifers with liver lesions induced by carbon tetrachloride, to determine the effect of the drug on blood components, enzymatic activities, and liver microsome functions. After injection of carbon tetrachloride, a decrease in
Z Z Zhang et al.
Hua xi yi ke da xue xue bao = Journal of West China University of Medical Sciences = Huaxi yike daxue xuebao, 20(1), 96-98 (1989-03-01)
In this paper, the early passage diploid Syrian hamster embryo (SHE) cells were used as the source of target. Four chemicals were appraised in SHE transformation test to determine whether they were carcinogens or not. They were (1) 2-benzoyl-hydrazono-1,3-diethiolane(BHD) (technical

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