InChI key
DSKJPMWIHSOYEA-RCIWAKOPSA-N
SMILES string
CC1=NC(NC([2H])([2H])C([2H])([2H])[2H])=NC(OS(N(C)C)(=O)=O)=C1CCCC
grade
analytical standard
product line
PESTANAL®
assay
≥98.0% (HPLC)
shelf life
limited shelf life, expiry date on the label
application(s)
agriculture
format
neat
storage temp.
2-8°C
Quality Level
General description
Bupirimate-(ethyl-d5) is an isotope-labeled analog of the local systemic fungicide bupirimate, wherein all the ethyl protons are replaced by deuterium.
Application
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Electrooxidation of bupirimate: a comparative study of SnO2 and boron doped diamond anodes
Errami M, et al.
International Journal of Electrochemical Science, 6, 4927-4938 (2011)
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