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78780

异硫氰酸苯酯

Name: 异硫氰酸苯酯
Brand: SIAL

for HPLC derivatization, the detection of alcohols and amines, ≥99.0%

别名:

PITC

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关于此项目

线性分子式:

C₆H₅NCS

化学文摘社编号:

103-72-0

分子量:

135.19

UNSPSC Code:

12352100

NACRES:

NA.21

PubChem Substance ID:

57652756

EC Number:

203-138-1

Beilstein/REAXYS Number:

471392

MDL number:

MFCD00004798

Assay:

≥99.0%

Form:

liquid

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Quality Level

200

assay

≥99.0%

form

liquid

quality

for HPLC derivatization, the detection of alcohols and amines

refractive index

n20/D 1.649, n20/D 1.6515 (lit.)

bp

218 °C (lit.)

mp

−21 °C (lit.)

solubility

water: insoluble

density

1.13 g/mL at 20 °C, 1.132 g/mL at 20 °C (lit.)

storage temp.

2-8°C

SMILES string

S=C=Nc1ccccc1

InChI

1S/C7H5NS/c9-6-8-7-4-2-1-3-5-7/h1-5H

InChI key

QKFJKGMPGYROCL-UHFFFAOYSA-N

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General description

异硫氰酸苯酯是芳香族异硫氰酸酯。它参与醇的脱水反应。它被广泛用于合成各种生物学上重要的杂环化合物。

Application

异硫氰酸苯酯可用作衍生化试剂，用于体液中各种苯丙胺衍生物的高效液相色谱（HPLC）分析。

用于伯胺和仲胺的衍生化试剂。用于通过 Edman 降解法进行多肽测序以及通过 HPLC 进行氨基酸分析。

Other Notes

发现用于 HPLC 或LC-MS 分析的理想LiChropur 试剂

Disclaimer

在氩气下存放

pictograms

GHS06,GHS08,GHS05

signalword

Danger

hcodes

H301,H314,H317,H334

pcodes

P261 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

190.4 °F - closed cup

flash_point_c

88 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

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One-pot dehydrations using phenyl isothiocyanate.

Majetich G, et al.

Tetrahedron Letters, 56(23), 3326-3329 (2015)

A convenient synthesis of 2-imino-1,3-thiazine-4-one derivatives from the reaction of primary amines and phenyl isothiocyanate in the presence of acryloyl chloride.

Amin Zolali et al.

Combinatorial chemistry & high throughput screening, 17(7), 610-613 (2014-03-19)

An efficient, one-pot and three-component synthesis of biologically important heterocyclic compounds is described from the reaction of primary amines and phenyl isothiocyanate in the presence of acryloyl chloride at room temperature without the need to use any catalyst.

Determination of phenylisothiocyanate derivatives of amphetamine and its analogues in biological fluids by HPLC-APCI-MS or DAD.

Bogusz MJ, et al.

Journal of Analytical Toxicology, 21(1), 59-69 (1997)

PEGylation of human serum albumin: reaction of PEG-phenyl-isothiocyanate with protein.

Fantao Meng et al.

Bioconjugate chemistry, 19(7), 1352-1360 (2008-06-25)

Successful and cost-effective PEGylation protocols require pure functionalized PEG reagents, which can be synthesized by simple and efficient procedures, exhibit high stability against hydrolysis, and maintain a level of reactivity with protein functional groups under mild reaction conditions. PEG-phenyl-isothiocyanate (PIT-PEG)

Application of statistical design for the optimization of amino acid separation by reverse-phase HPLC.

R Gheshlaghi et al.

Analytical biochemistry, 383(1), 93-102 (2008-08-30)

Modified resolution and overall separation factors used to quantify the separation of complex chromatography systems are described. These factors were proven to be applicable to the optimization of amino acid resolution in reverse-phase (RP) HPLC chromatograms. To optimize precolumn derivatization

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全球贸易项目编号

货号	GTIN
78780-25ML	04061832947266
78780-500ML	04061837370373
78780-100ML	04061832947259

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