InChI key
PGZVFRAEAAXREB-UHFFFAOYSA-N
InChI
1S/C10H18O3/c1-9(2,3)7(11)13-8(12)10(4,5)6/h1-6H3
SMILES string
CC(C)(C)C(=O)OC(=O)C(C)(C)C
grade
purum
assay
≥98.0% (GC)
refractive index
n20/D 1.409 (lit.), n20/D 1.409
bp
193 °C (lit.)
density
0.918 g/mL at 25 °C (lit.)
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Other Notes
This product has been replaced by 143502-ALDRICH | Trimethylacetic anhydride 99%
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
162.5 °F - closed cup
flash_point_c
72.5 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Isamu Shiina et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(1), 167-172 (2009-11-12)
A variety of optically active 2-hydroxyalkanoates and the corresponding 2-acyloxyalkanoates are produced by the kinetic resolution of racemic 2-hydroxyalkanoates by using achiral 2,2-diarylacetic acid with hindered carboxylic anhydrides as the coupling reagents. The combined use of diphenylacetic acid, pivalic anhydride
M Joppich et al.
Analytical biochemistry, 153(1), 159-165 (1986-02-15)
Reaction of thyroxine with ethanol and pivalic anhydride in the presence of 4-dimethylaminopyridine quantitatively forms N,O-dipivalyl thyroxine ethyl ester. Other iodothyronines react similarly and the procedure is moisture insensitive. Apparently this reaction is successful, in contrast to similar procedures reported
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