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Merck
CN

86490

2,2′:6′,2′′-三联吡啶

for spectrophotometric det. of Ag, Fe, Ru, ≥98.5%

别名:

α,α′,α″-三联吡啶, 2,6-Di(2-pyridyl)pyridine

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关于此项目

经验公式（希尔记法）:
C15H11N3
化学文摘社编号:
1148-79-4
分子量:
233.27
UNSPSC Code:
41115710
NACRES:
NA.21
PubChem Substance ID:
329769468
EC Number:
214-559-5
Beilstein/REAXYS Number:
11199
MDL number:
MFCD00006213

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InChI key

DRGAZIDRYFYHIJ-UHFFFAOYSA-N

InChI

1S/C15H11N3/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13/h1-11H

SMILES string

c1ccc(nc1)-c2cccc(n2)-c3ccccn3

assay

≥98.5% (GC), ≥98.5%

form

crystals

quality

for spectrophotometric det. of Ag, Fe, Ru

technique(s)

UV/Vis spectroscopy: suitable

mp

89-91 °C (lit.), 90-93 °C

solubility

dioxane: 0.1 g/mL, clear

cation traces

Ag: ≤5 mg/kg, Ba: ≤5 mg/kg, Ca: ≤5 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤5 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤5 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

Quality Level

100

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Packaging

无底玻璃瓶。内含物在插入的融合锥体内。

Other Notes

用于分光光度法测定 Ag 和 Ru 的试剂

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 1 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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L.C. Kamra et al.
Analytica Chimica Acta, 81, 177-177 (1976)
Queite A de Paula et al.
Dalton transactions (Cambridge, England : 2003), (48)(48), 10896-10903 (2009-12-22)
The reaction between the complexes [MCl(L)]Cl(x) (L = 2,2',2''-terpyridine, terpy and dien, diethylenetriamine; M = Pd, x = 1; M = Au, x = 2) and [Zn(bme-dach)](2), an N(2)S(2)-Zn-thiolate bridged dimer used to mimic zinc finger protein sites, was studied
H Inoue et al.
Nucleosides, nucleotides & nucleic acids, 20(4-7), 833-835 (2001-09-21)
An effective approach to promote sequence-specific RNA cleavage by an antisense 2'-O-methyloligonucleotide with a terpyridine.Cu(II) complex attached at the 5'-end was developed. We have synthesized a Cu(II) complex 3'-conjugate, which when used in a tandem fashion, greatly enhanced the RNA
W C Putnam et al.
Nucleic acids research, 29(10), 2199-2204 (2001-05-23)
Dramatic improvements in ribozyme mimics have been achieved by employing the principles of small molecule catalysis to the design of macromolecular, biomimetic reagents. Ribozyme mimics derived from the ligand 2,9-dimethylphenanthroline (neocuproine) show at least 30-fold improvements in efficiency at sequence-specific
E Sorenson et al.
European journal of biochemistry, 267(14), 4593-4599 (2000-07-06)
We recently reported that degradation of S-nitrosocysteine in homogenates of porcine aorta increased severalfold in the presence of Mg2+ ions [Kostka, P., Xu, B. & Skiles, E.H. (1999) J. Cardiovasc. Pharmacol. 33, 665-670]. The objective of the present study was
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