86843
四丁基氟化铵 三水合物
technical, ≥90% (T)
别名:
TBAF
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关于此项目
线性分子式:
[CH3(CH2)3]4NF · 3H2O
化学文摘社编号:
分子量:
315.51
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-057-2
Beilstein/REAXYS Number:
3761900
MDL number:
Assay:
≥90% (T)
Form:
crystals
InChI key
VEPTXBCIDSFGBF-UHFFFAOYSA-M
InChI
1S/C16H36N.FH.3H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;;;;/h5-16H2,1-4H3;1H;3*1H2/q+1;;;;/p-1
SMILES string
O.O.O.[F-].CCCC[N+](CCCC)(CCCC)CCCC
grade
technical
assay
≥90% (T)
form
crystals
mp
62-63 °C (lit.)
functional group
amine
Quality Level
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Application
反应物用于：
纤维素衍生物制备中脱保护剂的制备
用于体内 DNA 转染的亲脂性多肽的合成
脱氢溴化反应
纤维素衍生物制备中脱保护剂的制备
用于体内 DNA 转染的亲脂性多肽的合成
脱氢溴化反应
Tetrabutylammonium fluoride trihydrate may be used in the following studies:
- Synthesis of novel 3-O-(2-methoxyethyl)cellulose.
- To compose the novel solvent dimethyl sulfoxide (DMSO) /tetrabutylammonium fluoride trihydrate, used for the acetylation of linters cellulose.
- Synthesis of neutral organometallic fluoro complex.
- Synthesis of fluoroaromatic compounds.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Beatriz A P Ass et al.
Macromolecular bioscience, 4(11), 1008-1013 (2004-11-06)
The novel solvent dimethyl sulfoxide (DMSO)/tetrabutylammonium fluoride trihydrate (TBAF . 3H(2)O) was studied for acetylation of linters cellulose. In order to control the degree of substitution (DS), acetylation of the macromolecule was carried out at different reaction time and temperature
Fluorodenitrations using tetrabutylammonium fluoride.
Clark JH and Smith DK.
Tetrahedron Letters, 26(18), 2233-2236 (1985)
Effective preparation of cellulose derivatives in a new simple cellulose solvent.
Heinze T, et al.
Macromolecular Chemistry and Physics, 201(6), 627-631 (2000)
Thomas Heinze et al.
Carbohydrate research, 343(4), 668-673 (2008-02-12)
The synthesis of novel 3-O-(2-methoxyethyl)cellulose via 2,6-di-O-thexyldimethylsilyl ethers was successfully carried out. Treatments of 3-O-(2-methoxyethyl)-2,6-di-O-thexyldimethylsilylcellulose with tetrabutylammonium fluoride trihydrate led to a complete removal of the protecting groups. Structure characterization carried out by means of 1D and 2D NMR spectroscopy
Laurent Coue et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 10(8), 1906-1912 (2004-04-14)
The reaction of the complex [Mo(OTf)(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (1) (OTf = trifluoromethylsulfonate; phen = 1,10-phenanthroline) with tetrabutylammonium fluoride trihydrate afforded the fluoride complex [MoF(eta(3)-C(3)H(4)-Me-2)(CO)(2)(phen)] (2). The IR spectrum and the oxidation potential of 2 reflect the fact that its metal center is
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