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86853

Tetrabutylammonium hydrogen sulfate

suitable for ion pair chromatography, LiChropur™, ≥99.0%

别名:

Tetrabutylammonium hydrogen sulfate

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关于此项目

线性分子式:
(CH3CH2CH2CH2)4N(HSO4)
化学文摘社编号:
32503-27-8
分子量:
339.53
NACRES:
NB.21
PubChem Substance ID:
329769496
UNSPSC Code:
12352200
EC Number:
251-068-5
MDL number:
MFCD00011637
Beilstein/REAXYS Number:
3599663
Assay:
≥99.0% (T), ≥99.0%
Grade:
reagent grade
Form:
crystals
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产品名称

四丁基硫酸氢铵, suitable for ion pair chromatography, LiChropur™, ≥99.0%

grade

reagent grade

Quality Level

100

description

cationic

assay

≥99.0% (T), ≥99.0%

form

crystals

quality

LiChropur™

technique(s)

ion pair chromatography: suitable

mp

171-174 °C

anion traces

bromide (Br-): ≤50 mg/kg

λ

10 % in H2O

UV absorption

λ: 210 nm Amax: 0.06, λ: 220 nm Amax: 0.05, λ: 230 nm Amax: 0.03, λ: 260 nm Amax: 0.02, λ: 500 nm Amax: 0.02

suitability

corresponds to standard for RP gradient test, corresponds to standard for filter test

SMILES string

OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H2O4S/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1

InChI key

SHFJWMWCIHQNCP-UHFFFAOYSA-M

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相关类别

General description

四丁基硫酸氢铵(TBAHS) 是一种离子对试剂。它可以用作氮丙啶和环氧化物的水解催化剂，并且该催化剂可以循环使用。

Application

TBAHS适合作为离子对试剂，通过离子液体辅助离子对液液微萃取和电感耦合等离子体质谱法测定和分离铊。它适合作为HPLC-UV分析的流动相组分，对硫酸软骨素进行定量。

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1

存储类别

8A - Combustible corrosive hazardous materials

flash_point_f

348.1 °F - closed cup

flash_point_c

175.6 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN1351
BCCM9555
BCCL3753
BCCM4033
BCCJ9575

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Leticia B Escudero et al.
Journal of hazardous materials, 244-245, 380-386 (2012-12-29)
A fast and simple method involving separation and determination of thallium (Tl) species, based on novel ionic liquid-assisted ion pairing dispersive liquid-liquid microextraction (DLLME) method, was developed. Initially, Tl(III) was selectively complexed with chloride ion to form [TlCl(4)](-) chlorocomplex. Subsequently
David Ji et al.
Journal of AOAC International, 90(3), 659-669 (2007-06-22)
A method to quantify chondroitin sulfate in raw materials and dietary supplements at a range of about 5 to 100% (w/w) chondroitin sulfate has been developed and validated. The chondroitin sulfate is first selectively hydrolyzed by chondroitinase ACII enzyme to
Ren-Hua Fan et al.
Organic & biomolecular chemistry, 1(9), 1565-1567 (2003-08-21)
Bu4NHSO4 (TBAHS) is an effective catalyst for the hydrolysis of aziridines and epoxides under mild and non-metal conditions to give the corresponding beta-amino alcohols and 1,2-diols in high yields. The catalyst can be recycled.
K M Frankowski et al.
Journal of dairy science, 97(9), 5356-5370 (2014-07-16)
Many food companies are trying to limit the amount of sodium in their products. Permeate, the liquid remaining after whey or milk is ultrafiltered, has been suggested as a salt substitute. The objective of this study was to determine the
Erbo Shi et al.
Organic letters, 14(13), 3384-3387 (2012-06-27)
A metal-free C-H oxidation for the construction of allylic esters has been developed. The use of a commercially available and inexpensive catalyst and oxidant, and readily available starting materials, coupled with the operational simplicity of the reaction, renders the methodology
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实验方案

Analysis of Polar Compounds with Ion Pair Reagents

Reversed-phase HPLC sometimes requires ion pairing for adequate retention of polar compounds due to hydrophobic interactions.

全球贸易项目编号

货号GTIN
86853-1G-KC-F04061826679821
86853-50G-F04061835570867
86853-10X1G-F04061833380123
86853-10G-F04061835570850

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