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Merck
CN

87208

溴化十四烷基三甲基铵

suitable for ion pair chromatography, LiChropur, ≥99.0% (AT)

别名:

三甲基(十四烷基)溴化铵, 十四烷基三甲基溴化铵

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关于此项目

线性分子式:
CH3(CH2)13N(Br)(CH3)3
化学文摘社编号:
分子量:
336.39
UNSPSC Code:
23151817
NACRES:
NB.21
PubChem Substance ID:
EC Number:
214-291-9
Beilstein/REAXYS Number:
3633227
MDL number:
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InChI key

CXRFDZFCGOPDTD-UHFFFAOYSA-M

InChI

1S/C17H38N.BrH/c1-5-6-7-8-9-10-11-12-13-14-15-16-17-18(2,3)4;/h5-17H2,1-4H3;1H/q+1;/p-1

SMILES string

[Br-].CCCCCCCCCCCCCC[N+](C)(C)C

description

cationic

assay

≥99.0% (AT)

form

crystals

quality

LiChropur

mol wt

micellar avg mol wt 27,000

aggregation number

80

technique(s)

ion pair chromatography: suitable

CMC

4-5 mM (20-25°C)

mp

245-250 °C (lit.)

λ

10 % in H2O

UV absorption

λ: 240 nm Amax: ≤0.08, λ: 250 nm Amax: ≤0.05, λ: 260 nm Amax: ≤0.04, λ: 500 nm Amax: ≤0.02

suitability

corresponds to standard for filter test

Quality Level

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General description

Ion-pairing reagents as mobile phase additives facilitate the separation of ionic and highly polar substances on reversed phase HPLC columns. Their purity is an important parameter for their successful application. Sigma-Aldrich offers an wide range of tailor-made reagents for anionic (quaternary ammonium and phosphonium salts) and cationic (alkanesulfonates) analyzes. All mobile phase additives are subject to rigorous testing with special emphasis on the requirements of modern reversed phase HPLC:

Other Notes

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - STOT RE 2 Oral - STOT SE 3

target_organs

Gastrointestinal tract, Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Changcheng Liu et al.
The journal of physical chemistry. B, 114(30), 9795-9804 (2010-07-14)
The phase behavior, rheological properties, and structures of two salt-free catanionic surfactant systems, tetradecyltrimethylammonium hydroxide ((TTA)OH)/lauric acid (LA)/H(2)O and cetyltrimethylammonium hydroxide ((CTA)OH)/LA/H(2)O, in the presence of deoxycholic acid (DeCA) were investigated and compared with the results of cholic acid (CA).
Nuzhat Gull et al.
Colloids and surfaces. B, Biointerfaces, 69(1), 122-128 (2009-01-03)
The interaction of the cationic surfactant cetyltrimethylammonium bromide (CTAB) with bovine serum albumin (BSA), a globular protein, has been studied by small-angle neutron scattering (SANS), fluorescence and circular dichroism (CD). SANS measurements show that at low [CTAB] the protein shows
Sourabh Garg et al.
Bioresource technology, 121, 471-474 (2012-08-04)
This study aims to understand the underlying reasons for the poor flotation response of marine microalgae. The flotation performance and hydrophobicity of a freshwater microalga (Chlorella sp. BR2) were compared to those of a marine microalga (Tetraselmis sp. M8) at
A Zarbakhsh et al.
Langmuir : the ACS journal of surfaces and colloids, 25(7), 3953-3956 (2009-08-29)
We report information regarding the structure at the interface between hexadecane and an aqueous solution of trimethyl tetradecyl ammonium bromide (C14TAB) with appropriate deuterium labeling. We also report the role of the headgroup size and the charge on structures at
Suruchi Mahajan et al.
Langmuir : the ACS journal of surfaces and colloids, 28(50), 17238-17246 (2012-12-12)
Keeping in view the use of surfactants in drug delivery, the interactions of surface active ionic liquids, such as 1-tetradecyl-3-methylimidazolium bromide (C(14)mimBr), with drugs, viz., dopamine hydrochloride (DH) and acetylcholine chloride (AC), have been studied, and the results are further

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