88126
四丙基高钌酸铵
purum
别名:
TPAP
等级
purum
反应适用性
reagent type: oxidant
mp
~160 °C (dec.) (lit.)
储存温度
2-8°C
SMILES字符串
[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC
InChI
1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
InChI key
NQSIKKSFBQCBSI-UHFFFAOYSA-N
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其他说明
催化剂，用于在二氯甲烷中于 N-甲基吗啉-N-氧化物 (NMO) 介导下将醇温和氧化成羰基化合物
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
S.V. Ley et al.
Synthesis, 639-639 (1994)
Alexandra Fidalgo et al.
Physical chemistry chemical physics : PCCP, 10(15), 2026-2032 (2008-08-09)
Fluorinated organo-silica gels doped with tetra-n-propylammonium perruthenate (TPAP) are excellent catalysts for the aerobic oxidative dehydrogenation of alcohols in supercritical CO2 (scCO2). Their activity and stability are subtly dictated by structure, depending on the degree of fluorination and on the
C K Acosta et al.
Steroids, 58(5), 205-208 (1993-05-01)
Tetrapropylammonium perruthenate N-methylmorpholine N-oxide oxidation of steroidal alcohols is described. The reagent combination is mild and gave good yields of the corresponding ketones. Although the oxidation can generate ketones from 3-, 11-, 15-, 17-, and 20-hydroxy steroids, the oxidation of
A double donor-activated ruthenium(VII) catalyst: synthesis of enantiomerically pure THF-diols.
Huan Cheng et al.
Angewandte Chemie (International ed. in English), 49(9), 1587-1590 (2010-02-04)
Brooks E Maki et al.
Organic letters, 11(7), 1651-1654 (2009-03-27)
Indoles and alcohols can be coupled in a dehydrogenative process catalyzed by tetrapropylammonium perruthenate. This efficient approach to indolylamides proceeds in a single flask under mild conditions. By employing substituted indoles and alkyl, branched, or benzylic alcohols, a variety of
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