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88126

四丙基高钌酸铵

purum

别名:

TPAP

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关于此项目

线性分子式:
(CH3CH2CH2)4NRuO4
化学文摘社编号:
114615-82-6
分子量:
351.43
UNSPSC Code:
12352000
PubChem Substance ID:
24889060
MDL number:
MFCD00074914
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grade

purum

reaction suitability

reagent type: oxidant

mp

~160 °C (dec.) (lit.)

storage temp.

2-8°C

SMILES string

[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC

InChI

1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;

InChI key

NQSIKKSFBQCBSI-UHFFFAOYSA-N

Other Notes

催化剂，用于在二氯甲烷中于 N-甲基吗啉-N-氧化物 (NMO) 介导下将醇温和氧化成羰基化合物

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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Brooks E Maki et al.
Organic letters, 11(7), 1651-1654 (2009-03-27)
Indoles and alcohols can be coupled in a dehydrogenative process catalyzed by tetrapropylammonium perruthenate. This efficient approach to indolylamides proceeds in a single flask under mild conditions. By employing substituted indoles and alkyl, branched, or benzylic alcohols, a variety of
Alexandra Fidalgo et al.
Physical chemistry chemical physics : PCCP, 10(15), 2026-2032 (2008-08-09)
Fluorinated organo-silica gels doped with tetra-n-propylammonium perruthenate (TPAP) are excellent catalysts for the aerobic oxidative dehydrogenation of alcohols in supercritical CO2 (scCO2). Their activity and stability are subtly dictated by structure, depending on the degree of fluorination and on the
S.V. Ley et al.
Synthesis, 639-639 (1994)
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