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Merck
CN

89397

Supelco

吉拉尔特试剂 T

derivatization grade (HPLC), LiChropur™, 99.0-101.0% (AT)

别名:

(羧甲基)三甲基氯化铵酰肼, 乙酰肼三甲基氯化铵, 氯化三甲基铵乙酰肼

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关于此项目

线性分子式:
[(CH3)3N+CH2CONHNH2]Cl-
化学文摘社编号:
123-46-6
分子量:
167.64
Beilstein:
3727163
EC 号:
204-629-3
MDL编号:
MFCD00012009
UNSPSC代码:
12352200
PubChem化学物质编号:
329769730
NACRES:
NA.22

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等级

derivatization grade (HPLC)

质量水平

100

方案

99.0-101.0% (AT)

表单

crystals

质量

LiChropur™

技术

HPLC: suitable

mp

188-192 °C (dec.) (lit.)

SMILES字符串

[Cl-].C[N+](C)(C)CC(=O)NN

InChI

1S/C5H13N3O.ClH/c1-8(2,3)4-5(9)7-6;/h4,6H2,1-3H3;1H

InChI key

YSULOORXQBDPCU-UHFFFAOYSA-N

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应用

Girard′s reagent T may be used as a derivatizing reagent for the determination of 5-Formyl-2′-deoxyuridine in cellular DNA samples using liquid chromatography–tandem mass spectrometry (LC–MS/MS) technique. Reducing saccharides can be derivatized by Girard′s reagent T and this can be analyzed by matrix-assisted laser desorption/ionization coupled to time of flight mass spectrometry (MALDI-TOF-MS) technique.

特点和优势

  • Girard′s reagent T is a chemical derivatization reagent for LC-MS.
  • It has carbonyl functional group possessing high proton (cation) affinity that stabilizes a positive charge.       
  • It is commonly used in the derivatization of nucleosides.        
  • Derivatization reactions in mass spectrometry are used to improve ionization efficiency.
  • Derivatization can enhance precise quantitative analysis for profiling of relatively small analyte molecules, particularly in metabolomics.

其他说明

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCG6488
BCCF6003
BCCB5401
BCBZ5762
BCBW1699

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Oksana Lavrynenko et al.
Journal of lipid research, 54(8), 2265-2272 (2013-07-12)
Ecdysteroids are potent developmental regulators that control molting, reproduction, and stress response in arthropods. In developing larvae, picogram quantities of individual ecdysteroids and their conjugated forms are present along with milligrams of structural and energy storage lipids. To enhance the
Applications of MALDI-TOF Spectroscopy (2014)
Haizheng Hong et al.
Analytical chemistry, 79(1), 322-326 (2006-12-30)
Nucleoside 5-formyl-2'-deoxyuridine (FodU) is a major thymidine lesion generated by reactive oxygen species. In vitro and in vivo replication studies revealed that FodU can be mutagenic. A reliable and sensitive quantification method is, therefore, important for assessing the biological implications

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